Synthesis, crystal structure and Hirshfeld surface analysis of di­acetato­bis­[4-(2-amino­eth­yl)morpholine]cadmium tetra­hydrate

The title coordination compound, [Cd(C(2)H(3)O(2))(2)(C(6)H(14)N(2)O)(2)]·4H(2)O, was synthesized by mixing 2 moles of 4-(2-amino­eth­yl)morpholine and 1 mole of cadmium acetate in double-distilled water. The Cd atom is octa­hedrally coord­inated by two N,N′-bidentate ligands [4-(2-amino­eth­yl)morpholine] and two trans-located acetate mol­ecules. The Cd atom is located on a center of inversion, whereas the 4-(2-amino­eth­yl)morpholine and four water mol­ecules are adjacent to the acetate mol­ecules. The chair conformation of the morpholine mol­ecules is confirmed. In the crystal, adjacent metal complexes and uncoord­inated water mol­ecules are linked via N—H⋯O and O—H⋯O hydrogen-bonding inter­actions, generating R (2) (2)(6), R (6) (6)(16), R (6) (6)(20) and S (1) (1)(6) motifs and forming a three-dimensional network. A Hirshfeld surface analysis indicated the contributions of various contacts: H⋯H (71.8%), O⋯H/H⋯O (27.1%), and C⋯H/H⋯C (1.0%).