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Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene

In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating ord...

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Detalles Bibliográficos
Autores principales: Stapf, Manuel, Schmidt, Ute, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626963/
https://www.ncbi.nlm.nih.gov/pubmed/37936864
http://dx.doi.org/10.1107/S2056989023009155
Descripción
Sumario:In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supra­molecular architecture, while the crystal structure of 1b consists of two-dimensional supra­molecular aggregates extending parallel to the crystallographic ab plane.