Cargando…

Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene

In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating ord...

Descripción completa

Detalles Bibliográficos
Autores principales: Stapf, Manuel, Schmidt, Ute, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626963/
https://www.ncbi.nlm.nih.gov/pubmed/37936864
http://dx.doi.org/10.1107/S2056989023009155
_version_ 1785131441369120768
author Stapf, Manuel
Schmidt, Ute
Seichter, Wilhelm
Mazik, Monika
author_facet Stapf, Manuel
Schmidt, Ute
Seichter, Wilhelm
Mazik, Monika
author_sort Stapf, Manuel
collection PubMed
description In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supra­molecular architecture, while the crystal structure of 1b consists of two-dimensional supra­molecular aggregates extending parallel to the crystallographic ab plane.
format Online
Article
Text
id pubmed-10626963
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-106269632023-11-07 Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene Stapf, Manuel Schmidt, Ute Seichter, Wilhelm Mazik, Monika Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supra­molecular architecture, while the crystal structure of 1b consists of two-dimensional supra­molecular aggregates extending parallel to the crystallographic ab plane. International Union of Crystallography 2023-10-24 /pmc/articles/PMC10626963/ /pubmed/37936864 http://dx.doi.org/10.1107/S2056989023009155 Text en © Stapf et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Stapf, Manuel
Schmidt, Ute
Seichter, Wilhelm
Mazik, Monika
Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title_full Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title_fullStr Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title_full_unstemmed Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title_short Synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
title_sort synthesis and crystal structures of two solvates of 1-{[2,6-bis­(hy­droxy­meth­yl)-4-methyl­phen­oxy]meth­yl}-3,5-bis­{[(4,6-di­methyl­pyridin-2-yl)amino]meth­yl}-2,4,6-tri­ethyl­benzene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626963/
https://www.ncbi.nlm.nih.gov/pubmed/37936864
http://dx.doi.org/10.1107/S2056989023009155
work_keys_str_mv AT stapfmanuel synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene
AT schmidtute synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene
AT seichterwilhelm synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene
AT mazikmonika synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene