Cargando…
Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene
In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host molecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating ord...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626963/ https://www.ncbi.nlm.nih.gov/pubmed/37936864 http://dx.doi.org/10.1107/S2056989023009155 |
_version_ | 1785131441369120768 |
---|---|
author | Stapf, Manuel Schmidt, Ute Seichter, Wilhelm Mazik, Monika |
author_facet | Stapf, Manuel Schmidt, Ute Seichter, Wilhelm Mazik, Monika |
author_sort | Stapf, Manuel |
collection | PubMed |
description | In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host molecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supramolecular architecture, while the crystal structure of 1b consists of two-dimensional supramolecular aggregates extending parallel to the crystallographic ab plane. |
format | Online Article Text |
id | pubmed-10626963 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-106269632023-11-07 Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene Stapf, Manuel Schmidt, Ute Seichter, Wilhelm Mazik, Monika Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H(2)O solvate/hydrate (1b) of the title compound, C(38)H(50)N(4)O(3) (1), the tripodal host molecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supramolecular architecture, while the crystal structure of 1b consists of two-dimensional supramolecular aggregates extending parallel to the crystallographic ab plane. International Union of Crystallography 2023-10-24 /pmc/articles/PMC10626963/ /pubmed/37936864 http://dx.doi.org/10.1107/S2056989023009155 Text en © Stapf et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Stapf, Manuel Schmidt, Ute Seichter, Wilhelm Mazik, Monika Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title | Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title_full | Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title_fullStr | Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title_full_unstemmed | Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title_short | Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
title_sort | synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626963/ https://www.ncbi.nlm.nih.gov/pubmed/37936864 http://dx.doi.org/10.1107/S2056989023009155 |
work_keys_str_mv | AT stapfmanuel synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene AT schmidtute synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene AT seichterwilhelm synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene AT mazikmonika synthesisandcrystalstructuresoftwosolvatesof126bishydroxymethyl4methylphenoxymethyl35bis46dimethylpyridin2ylaminomethyl246triethylbenzene |