Cargando…
Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate]
The title compound, [FeLi(2)(C(12)H(12)N(12)O(6))(H(2)O)(4)]·4H(2)O, consists of iron complex anions, lithium cations and water molecules. The complex anion shows a clathrochelate topology. The coordination geometry of the Fe(IV) centre is intermediate between a trigonal prism and a trigonal anti...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626965/ https://www.ncbi.nlm.nih.gov/pubmed/37936846 http://dx.doi.org/10.1107/S2056989023008587 |
| _version_ | 1785131441871388672 |
|---|---|
| author | Plutenko, Maksym O. Shova, Sergiu Pavlenko, Vadim A. Golenya, Irina A. Fritsky, Igor O. |
| author_facet | Plutenko, Maksym O. Shova, Sergiu Pavlenko, Vadim A. Golenya, Irina A. Fritsky, Igor O. |
| author_sort | Plutenko, Maksym O. |
| collection | PubMed |
| description | The title compound, [FeLi(2)(C(12)H(12)N(12)O(6))(H(2)O)(4)]·4H(2)O, consists of iron complex anions, lithium cations and water molecules. The complex anion shows a clathrochelate topology. The coordination geometry of the Fe(IV) centre is intermediate between a trigonal prism and a trigonal antiprism. In the crystal, the complex anions are connected through two Li cations into dimers, which are connected by Li—O bonds, forming infinite chains along the b-axis direction. |
| format | Online Article Text |
| id | pubmed-10626965 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-106269652023-11-07 Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] Plutenko, Maksym O. Shova, Sergiu Pavlenko, Vadim A. Golenya, Irina A. Fritsky, Igor O. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [FeLi(2)(C(12)H(12)N(12)O(6))(H(2)O)(4)]·4H(2)O, consists of iron complex anions, lithium cations and water molecules. The complex anion shows a clathrochelate topology. The coordination geometry of the Fe(IV) centre is intermediate between a trigonal prism and a trigonal antiprism. In the crystal, the complex anions are connected through two Li cations into dimers, which are connected by Li—O bonds, forming infinite chains along the b-axis direction. International Union of Crystallography 2023-10-19 /pmc/articles/PMC10626965/ /pubmed/37936846 http://dx.doi.org/10.1107/S2056989023008587 Text en © Plutenko et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Plutenko, Maksym O. Shova, Sergiu Pavlenko, Vadim A. Golenya, Irina A. Fritsky, Igor O. Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title | Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title_full | Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title_short | Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate] |
| title_sort | crystal structure and hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.1(3,17).1(8,12)]tetracosane-5,6,14,15,20,21-hexaonato)iron(iv)dilithium] tetrahydrate] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626965/ https://www.ncbi.nlm.nih.gov/pubmed/37936846 http://dx.doi.org/10.1107/S2056989023008587 |
| work_keys_str_mv | AT plutenkomaksymo crystalstructureandhirshfeldsurfaceanalysisofpolytetraaquam1347810121316171922dodecaazatetracyclo88413171812tetracosane5614152021hexaonatoironivdilithiumtetrahydrate AT shovasergiu crystalstructureandhirshfeldsurfaceanalysisofpolytetraaquam1347810121316171922dodecaazatetracyclo88413171812tetracosane5614152021hexaonatoironivdilithiumtetrahydrate AT pavlenkovadima crystalstructureandhirshfeldsurfaceanalysisofpolytetraaquam1347810121316171922dodecaazatetracyclo88413171812tetracosane5614152021hexaonatoironivdilithiumtetrahydrate AT golenyairinaa crystalstructureandhirshfeldsurfaceanalysisofpolytetraaquam1347810121316171922dodecaazatetracyclo88413171812tetracosane5614152021hexaonatoironivdilithiumtetrahydrate AT fritskyigoro crystalstructureandhirshfeldsurfaceanalysisofpolytetraaquam1347810121316171922dodecaazatetracyclo88413171812tetracosane5614152021hexaonatoironivdilithiumtetrahydrate |