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Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans
A novel magnetic silica/graphene oxide nanocomposite supported ionic liquid/manganese complex (Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn) is prepared, characterized and its catalytic application is investigated. The Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn catalyst was synthesized via chemical immobilization of graphe...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630333/ https://www.ncbi.nlm.nih.gov/pubmed/37935907 http://dx.doi.org/10.1038/s41598-023-46629-4 |
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author | Dadvar, Farkhondeh Elhamifar, Dawood |
author_facet | Dadvar, Farkhondeh Elhamifar, Dawood |
author_sort | Dadvar, Farkhondeh |
collection | PubMed |
description | A novel magnetic silica/graphene oxide nanocomposite supported ionic liquid/manganese complex (Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn) is prepared, characterized and its catalytic application is investigated. The Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn catalyst was synthesized via chemical immobilization of graphene oxide on Fe(3)O(4)@SiO(2) nanoparticles followed by modification with ionic liquid/Mn complex. This nanocomposite was characterized by using SEM, TGA, FT-IR, PXRD, EDX, TEM, nitrogen adsorption–desorption, and VSM analyses. The catalytic application of Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn was studied in the synthesis of tetrahydrobenzo[b]pyrans (THBPs) in water solvent at RT. This nanocatalyst was successfully recovered and reused at least eight times without a significant decrease in its activity. |
format | Online Article Text |
id | pubmed-10630333 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-106303332023-11-07 Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans Dadvar, Farkhondeh Elhamifar, Dawood Sci Rep Article A novel magnetic silica/graphene oxide nanocomposite supported ionic liquid/manganese complex (Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn) is prepared, characterized and its catalytic application is investigated. The Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn catalyst was synthesized via chemical immobilization of graphene oxide on Fe(3)O(4)@SiO(2) nanoparticles followed by modification with ionic liquid/Mn complex. This nanocomposite was characterized by using SEM, TGA, FT-IR, PXRD, EDX, TEM, nitrogen adsorption–desorption, and VSM analyses. The catalytic application of Fe(3)O(4)@SiO(2)-NH(2)/GO/IL-Mn was studied in the synthesis of tetrahydrobenzo[b]pyrans (THBPs) in water solvent at RT. This nanocatalyst was successfully recovered and reused at least eight times without a significant decrease in its activity. Nature Publishing Group UK 2023-11-07 /pmc/articles/PMC10630333/ /pubmed/37935907 http://dx.doi.org/10.1038/s41598-023-46629-4 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Dadvar, Farkhondeh Elhamifar, Dawood Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title | Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title_full | Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title_fullStr | Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title_full_unstemmed | Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title_short | Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
title_sort | magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630333/ https://www.ncbi.nlm.nih.gov/pubmed/37935907 http://dx.doi.org/10.1038/s41598-023-46629-4 |
work_keys_str_mv | AT dadvarfarkhondeh magneticsilicagrapheneoxidenanocompositesupportedionicliquidmanganesecomplexasapowerfulcatalystforthesynthesisoftetrahydrobenzopyrans AT elhamifardawood magneticsilicagrapheneoxidenanocompositesupportedionicliquidmanganesecomplexasapowerfulcatalystforthesynthesisoftetrahydrobenzopyrans |