Cargando…
Nitrenium ions as new versatile reagents for electrophilic amination
Herein we report the utilization of N-heterocyclic nitrenium ions – easily prepared, bench-stable and non-oxidating nitrogen sources for the efficient electrophilic amination of aliphatic and aromatic organometallic nucleophiles, towards the facile and general preparation of primary amines. To this...
Autores principales: | Avigdori, Idan, Singh, Kuldeep, Fridman, Natalia, Gandelman, Mark |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631241/ https://www.ncbi.nlm.nih.gov/pubmed/37969608 http://dx.doi.org/10.1039/d3sc04268e |
Ejemplares similares
-
The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines
por: Gasser, Valentina C. M., et al.
Publicado: (2022) -
Discrete Existence of Singlet Nitrenium Ions Revisited:
Computational Studies of Non-Aryl Nitrenium Ions and Their Rearrangements
por: Falvey, Daniel E.
Publicado: (2018) -
Phenothiazinimides: Atom-Efficient Electrophilic Amination
Reagents
por: Jin, Rongwei, et al.
Publicado: (2018) -
Observation of electrochemically generated nitrenium ions by desorption electrospray ionization mass spectrometry
por: Brown, Timothy A., et al.
Publicado: (2016) -
General stereoretentive preparation of chiral secondary mixed alkylmagnesium reagents and their use for enantioselective electrophilic aminations
por: Kremsmair, Alexander, et al.
Publicado: (2021)