Borylation directed borylation of N-alkyl anilines using iodine activated pyrazaboles

Doubly electrophilic pyrazabole derivatives (pyrazabole = [H(2)B(μ-C(3)N(2)H(3))](2)) combined with one equiv. of base effect the ortho-borylation of N-alkyl anilines. Initial studies found that the bis(trifluoromethane)sulfonimide ([NTf(2)](−)) pyrazabole derivative, [H(NTf(2))B(μ-C(3)N(2)H(3))](2)...

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Detalles Bibliográficos
Autores principales: Millet, C. R. P., Noone, E., Schellbach, A. V., Pahl, J., Łosiewicz, J., Nichol, G. S., Ingleson, M. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631245/
https://www.ncbi.nlm.nih.gov/pubmed/37969579
http://dx.doi.org/10.1039/d3sc04269c

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