Divergent 1,2-carboallylation of terminal alkynes enabled by metallaphotoredox catalysis with switchable triplet energy transfer

We report a metallaphotoredox strategy for stereodivergent three-component carboallylation of terminal alkynes with allylic carbonates and alkyl trifluoroborates. This redox-neutral dual catalytic protocol utilizes commercially available organic photocatalyst 4CzIPN and nickel catalysts to trigger a...

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Detalles Bibliográficos
Autores principales: Qin, Jian, Zhang, Zhuzhu, Lu, Yi, Zhu, Shengqing, Chu, Lingling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631246/
https://www.ncbi.nlm.nih.gov/pubmed/37969584
http://dx.doi.org/10.1039/d3sc04645a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631246/
https://www.ncbi.nlm.nih.gov/pubmed/37969584
http://dx.doi.org/10.1039/d3sc04645a

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