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Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane

[Image: see text] Rapid formation of the CO(2) hydrate can be significantly induced by the gaseous thermodynamic promoter 1,1,1,2-tetrafluoroethane(R134a) due to the mild phase equilibrium conditions, although the formation mechanism and dynamic behavior are not clear. Therefore, a visual experiment...

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Autores principales: Song, Tianyi, Zhang, Jinhai, Li, Wei, Ma, Jie, Hu, Shen, Liu, Jianxiu, Li, Xiaonan, Hu, Wenfeng, Lan, Chunming, Tian, Guohua, Jin, Tingxiang, Han, Yuexin, Wang, Jiancheng, Gong, Junjie, Cheng, Chuanxiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10633894/
https://www.ncbi.nlm.nih.gov/pubmed/37970053
http://dx.doi.org/10.1021/acsomega.3c04578
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author Song, Tianyi
Zhang, Jinhai
Li, Wei
Ma, Jie
Hu, Shen
Liu, Jianxiu
Li, Xiaonan
Hu, Wenfeng
Lan, Chunming
Tian, Guohua
Jin, Tingxiang
Han, Yuexin
Wang, Jiancheng
Gong, Junjie
Cheng, Chuanxiao
author_facet Song, Tianyi
Zhang, Jinhai
Li, Wei
Ma, Jie
Hu, Shen
Liu, Jianxiu
Li, Xiaonan
Hu, Wenfeng
Lan, Chunming
Tian, Guohua
Jin, Tingxiang
Han, Yuexin
Wang, Jiancheng
Gong, Junjie
Cheng, Chuanxiao
author_sort Song, Tianyi
collection PubMed
description [Image: see text] Rapid formation of the CO(2) hydrate can be significantly induced by the gaseous thermodynamic promoter 1,1,1,2-tetrafluoroethane(R134a) due to the mild phase equilibrium conditions, although the formation mechanism and dynamic behavior are not clear. Therefore, a visual experimental system was developed to study the effects of different concentrations of R134a on the induction time, gas consumption, and growth morphology of the CO(2) hydrate. At the same time, the combined effects under stirring and sodium dodecyl sulfate (SDS) systems were also studied. In addition, visualization and experimental model diagrams were combined to explain the fast formation mechanism of the R134a/CO(2) hydrate. The results show that the CO(2) hydrate average conversion rate was increased by more than 63% with the addition of mixed trace R134a(7%). A special phenomenon is found that two temperature peaks appear on the hydrate formation temperature curve, corresponding to two different stages of hydrate formation when stirring or SDS is added to the mixed gas reaction system. Furthermore, the gas consumption in stirring and SDS systems increases by 9 and 44%, respectively. Finally, it is also found that the R134a/CO(2) mixed hydrate formed under the action of SDS has a “capillary” mechanism, which provides a gas–liquid phase exchange channel and a large number of nucleation sites for CO(2) hydrate, thus promoting the formation of CO(2) hydrate. This paper provides a novel, simple, and efficient method for CO(2) hydrate gas storage technology.
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spelling pubmed-106338942023-11-15 Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane Song, Tianyi Zhang, Jinhai Li, Wei Ma, Jie Hu, Shen Liu, Jianxiu Li, Xiaonan Hu, Wenfeng Lan, Chunming Tian, Guohua Jin, Tingxiang Han, Yuexin Wang, Jiancheng Gong, Junjie Cheng, Chuanxiao ACS Omega [Image: see text] Rapid formation of the CO(2) hydrate can be significantly induced by the gaseous thermodynamic promoter 1,1,1,2-tetrafluoroethane(R134a) due to the mild phase equilibrium conditions, although the formation mechanism and dynamic behavior are not clear. Therefore, a visual experimental system was developed to study the effects of different concentrations of R134a on the induction time, gas consumption, and growth morphology of the CO(2) hydrate. At the same time, the combined effects under stirring and sodium dodecyl sulfate (SDS) systems were also studied. In addition, visualization and experimental model diagrams were combined to explain the fast formation mechanism of the R134a/CO(2) hydrate. The results show that the CO(2) hydrate average conversion rate was increased by more than 63% with the addition of mixed trace R134a(7%). A special phenomenon is found that two temperature peaks appear on the hydrate formation temperature curve, corresponding to two different stages of hydrate formation when stirring or SDS is added to the mixed gas reaction system. Furthermore, the gas consumption in stirring and SDS systems increases by 9 and 44%, respectively. Finally, it is also found that the R134a/CO(2) mixed hydrate formed under the action of SDS has a “capillary” mechanism, which provides a gas–liquid phase exchange channel and a large number of nucleation sites for CO(2) hydrate, thus promoting the formation of CO(2) hydrate. This paper provides a novel, simple, and efficient method for CO(2) hydrate gas storage technology. American Chemical Society 2023-10-25 /pmc/articles/PMC10633894/ /pubmed/37970053 http://dx.doi.org/10.1021/acsomega.3c04578 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Song, Tianyi
Zhang, Jinhai
Li, Wei
Ma, Jie
Hu, Shen
Liu, Jianxiu
Li, Xiaonan
Hu, Wenfeng
Lan, Chunming
Tian, Guohua
Jin, Tingxiang
Han, Yuexin
Wang, Jiancheng
Gong, Junjie
Cheng, Chuanxiao
Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title_full Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title_fullStr Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title_full_unstemmed Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title_short Rapid Growth of the CO(2) Hydrate Induced by Mixing Trace Tetrafluoroethane
title_sort rapid growth of the co(2) hydrate induced by mixing trace tetrafluoroethane
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10633894/
https://www.ncbi.nlm.nih.gov/pubmed/37970053
http://dx.doi.org/10.1021/acsomega.3c04578
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