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Absence of Superconductivity in LK-99 at Ambient Conditions
[Image: see text] The report of the synthesis of modified lead apatite (LK-99), with evidence of superconductivity at more than boiling water temperature, has steered the scientific community. There have been several failures to reproduce superconductivity in LK-99, despite partial successes. Here,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10633996/ https://www.ncbi.nlm.nih.gov/pubmed/37969980 http://dx.doi.org/10.1021/acsomega.3c06096 |
Sumario: | [Image: see text] The report of the synthesis of modified lead apatite (LK-99), with evidence of superconductivity at more than boiling water temperature, has steered the scientific community. There have been several failures to reproduce superconductivity in LK-99, despite partial successes. Here, we have continued our efforts to synthesize phase-pure LK-99 with improved precursors. The synthesis process being followed is the same as suggested by Sukbae Lee et al. The phase purity of each precursor is evidenced by powder X-ray diffraction (PXRD) and is well-fitted by Rietveld refinement. The PXRD confirms the synthesis of phase-pure polycrystalline LK-99 with a lead apatite structure. The sample is highly resistive, showing insulator-like behavior in resistivity measurement in the temperature range from 215 to 325 K, which confirms the absence of superconductivity in synthesized LK-99 at room temperature. The magnetization measurements of LK-99 on the SQUID magnetometer resemble the behavior of a resistive diamagnetic material at 280 K. Moreover, we have also performed first principle calculations to investigate the electronic band structure of LK-99 in the vicinity of the Fermi level. Our study verifies that the copper (Cu)-doped lead apatite (LK-99) exhibits band crossing at the Fermi level, indicating the generation of strong correlation in the presently studied system. Our experimental results do not approve the appearance of superconductivity in LK-99, i.e., Pb(9)CuP(6)O(25). |
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