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Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition

[Image: see text] In this research work, a material system formed of cadmium sulfide combined with chromium atoms was developed to evaluate the influence of chromium concentration on the optical, electrical, structural, and morphological properties of a precursor layer of CdS. It is possible to obse...

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Autores principales: Contreras-Rodriguez, R. R., Mendivil-Reynoso, T., Landin, Isaias Ochoa, Castillo, S. J., Ochoa-Landín, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10634208/
https://www.ncbi.nlm.nih.gov/pubmed/37970057
http://dx.doi.org/10.1021/acsomega.3c05003
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author Contreras-Rodriguez, R. R.
Mendivil-Reynoso, T.
Landin, Isaias Ochoa
Castillo, S. J.
Ochoa-Landín, R.
author_facet Contreras-Rodriguez, R. R.
Mendivil-Reynoso, T.
Landin, Isaias Ochoa
Castillo, S. J.
Ochoa-Landín, R.
author_sort Contreras-Rodriguez, R. R.
collection PubMed
description [Image: see text] In this research work, a material system formed of cadmium sulfide combined with chromium atoms was developed to evaluate the influence of chromium concentration on the optical, electrical, structural, and morphological properties of a precursor layer of CdS. It is possible to observe that the transmission spectra increased for all chromium concentrations analyzed. From X-ray diffractograms, we conclude more accurately that CdS presents a mixture of phases, including orthorhombic, hexagonal, and cubic. Furthermore, the impact of adding chromium results in variations in the intensity of two major peaks in the diffractograms and an anomalous shift in the CdS pattern. The calculated resistivities show an invariable behavior of 4.5 × 10(6) Ω cm. In addition, the bandgap values remain practically constant, with values of approximately 2.43–2.44 eV. The addition of chromium at different concentrations leads to surface morphology changes, as observed in SEM images.
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spelling pubmed-106342082023-11-15 Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition Contreras-Rodriguez, R. R. Mendivil-Reynoso, T. Landin, Isaias Ochoa Castillo, S. J. Ochoa-Landín, R. ACS Omega [Image: see text] In this research work, a material system formed of cadmium sulfide combined with chromium atoms was developed to evaluate the influence of chromium concentration on the optical, electrical, structural, and morphological properties of a precursor layer of CdS. It is possible to observe that the transmission spectra increased for all chromium concentrations analyzed. From X-ray diffractograms, we conclude more accurately that CdS presents a mixture of phases, including orthorhombic, hexagonal, and cubic. Furthermore, the impact of adding chromium results in variations in the intensity of two major peaks in the diffractograms and an anomalous shift in the CdS pattern. The calculated resistivities show an invariable behavior of 4.5 × 10(6) Ω cm. In addition, the bandgap values remain practically constant, with values of approximately 2.43–2.44 eV. The addition of chromium at different concentrations leads to surface morphology changes, as observed in SEM images. American Chemical Society 2023-10-23 /pmc/articles/PMC10634208/ /pubmed/37970057 http://dx.doi.org/10.1021/acsomega.3c05003 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Contreras-Rodriguez, R. R.
Mendivil-Reynoso, T.
Landin, Isaias Ochoa
Castillo, S. J.
Ochoa-Landín, R.
Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title_full Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title_fullStr Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title_full_unstemmed Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title_short Optical, Electrical, and Morphologic Characterization of Chromium-Impurified CdS Thin Films Elaborated by the Chemical Bath Deposition
title_sort optical, electrical, and morphologic characterization of chromium-impurified cds thin films elaborated by the chemical bath deposition
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10634208/
https://www.ncbi.nlm.nih.gov/pubmed/37970057
http://dx.doi.org/10.1021/acsomega.3c05003
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