Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides

A simple approach for copper-promoted S-arylation reactions utilizing triarylbismuths or triarylantimonys as arylating reagents has been described. These reactions can be performed under mild conditions and exhibit remarkable functional group tolerance and chemoselectivity. The corresponding 2-arylt...

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Autores principales: Nie, Mei, Zhou, Xuehao, Tang, Jingjie, Huang, Dongting, Xiao, Xinsheng, Xie, Jianwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636603/
https://www.ncbi.nlm.nih.gov/pubmed/37954419
http://dx.doi.org/10.1039/d3ra06582k
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author Nie, Mei
Zhou, Xuehao
Tang, Jingjie
Huang, Dongting
Xiao, Xinsheng
Xie, Jianwei
author_facet Nie, Mei
Zhou, Xuehao
Tang, Jingjie
Huang, Dongting
Xiao, Xinsheng
Xie, Jianwei
author_sort Nie, Mei
collection PubMed
description A simple approach for copper-promoted S-arylation reactions utilizing triarylbismuths or triarylantimonys as arylating reagents has been described. These reactions can be performed under mild conditions and exhibit remarkable functional group tolerance and chemoselectivity. The corresponding 2-arylthiopyridine 1-oxide derivatives and arylthioanilines/phenols have been successfully synthesized, achieving good to excellent yields across over 49 examples.
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spelling pubmed-106366032023-11-11 Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides Nie, Mei Zhou, Xuehao Tang, Jingjie Huang, Dongting Xiao, Xinsheng Xie, Jianwei RSC Adv Chemistry A simple approach for copper-promoted S-arylation reactions utilizing triarylbismuths or triarylantimonys as arylating reagents has been described. These reactions can be performed under mild conditions and exhibit remarkable functional group tolerance and chemoselectivity. The corresponding 2-arylthiopyridine 1-oxide derivatives and arylthioanilines/phenols have been successfully synthesized, achieving good to excellent yields across over 49 examples. The Royal Society of Chemistry 2023-11-10 /pmc/articles/PMC10636603/ /pubmed/37954419 http://dx.doi.org/10.1039/d3ra06582k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Nie, Mei
Zhou, Xuehao
Tang, Jingjie
Huang, Dongting
Xiao, Xinsheng
Xie, Jianwei
Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title_full Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title_fullStr Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title_full_unstemmed Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title_short Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
title_sort copper-promoted s-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636603/
https://www.ncbi.nlm.nih.gov/pubmed/37954419
http://dx.doi.org/10.1039/d3ra06582k
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