Radical and Cationic Pathways in C(sp(3))–H Bond Oxygenation by Dioxiranes of Bicyclic and Spirocyclic Hydrocarbons Bearing Cyclopropane Moieties

[Image: see text] A product and DFT computational study on the reactions of 3-ethyl-3-(trifluoromethyl)dioxirane (ETFDO) with bicyclic and spirocyclic hydrocarbons bearing cyclopropyl groups was carried out. With bicyclo[n.1.0]alkanes (n = 3–6), diastereoselective formation of the alcohol product de...

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Detalles Bibliográficos
Autores principales: Galeotti, Marco, Lee, Woojin, Sisti, Sergio, Casciotti, Martina, Salamone, Michela, Houk, K. N., Bietti, Massimo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636757/
https://www.ncbi.nlm.nih.gov/pubmed/37874906
http://dx.doi.org/10.1021/jacs.3c07163

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636757/
https://www.ncbi.nlm.nih.gov/pubmed/37874906
http://dx.doi.org/10.1021/jacs.3c07163

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