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Uniform Semiclassical Instanton Rate Theory

[Image: see text] The instanton expression for the thermal transmission probability through a one-dimensional barrier is derived by using the uniform semiclassical energy-dependent transmission coefficient of Kemble. The resulting theory does not diverge at the “crossover temperature” but changes sm...

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Detalles Bibliográficos
Autores principales: Upadhyayula, Sameernandan, Pollak, Eli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10641875/
https://www.ncbi.nlm.nih.gov/pubmed/37906954
http://dx.doi.org/10.1021/acs.jpclett.3c02779

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