Cargando…

Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals

To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexes in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of t...

Descripción completa

Detalles Bibliográficos
Autores principales: Mei, Peifeng, Morimoto, Hirofumi, Okada, Yuta, Matsuo, Kyohei, Hayashi, Hironobu, Saeki, Akinori, Yamada, Hiroko, Aratani, Naoki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10644901/
https://www.ncbi.nlm.nih.gov/pubmed/38025867
http://dx.doi.org/10.1039/d3ra06526j
_version_ 1785147292283568128
author Mei, Peifeng
Morimoto, Hirofumi
Okada, Yuta
Matsuo, Kyohei
Hayashi, Hironobu
Saeki, Akinori
Yamada, Hiroko
Aratani, Naoki
author_facet Mei, Peifeng
Morimoto, Hirofumi
Okada, Yuta
Matsuo, Kyohei
Hayashi, Hironobu
Saeki, Akinori
Yamada, Hiroko
Aratani, Naoki
author_sort Mei, Peifeng
collection PubMed
description To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexes in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C(60)@N6 composite have semiconductive properties revealed by photoconductivity measurements.
format Online
Article
Text
id pubmed-10644901
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-106449012023-11-14 Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals Mei, Peifeng Morimoto, Hirofumi Okada, Yuta Matsuo, Kyohei Hayashi, Hironobu Saeki, Akinori Yamada, Hiroko Aratani, Naoki RSC Adv Chemistry To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexes in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C(60)@N6 composite have semiconductive properties revealed by photoconductivity measurements. The Royal Society of Chemistry 2023-11-14 /pmc/articles/PMC10644901/ /pubmed/38025867 http://dx.doi.org/10.1039/d3ra06526j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Mei, Peifeng
Morimoto, Hirofumi
Okada, Yuta
Matsuo, Kyohei
Hayashi, Hironobu
Saeki, Akinori
Yamada, Hiroko
Aratani, Naoki
Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title_full Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title_fullStr Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title_full_unstemmed Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title_short Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C(60) and C(70) in solution and 1D-alignment of fullerenes in the crystals
title_sort complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes c(60) and c(70) in solution and 1d-alignment of fullerenes in the crystals
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10644901/
https://www.ncbi.nlm.nih.gov/pubmed/38025867
http://dx.doi.org/10.1039/d3ra06526j
work_keys_str_mv AT meipeifeng complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT morimotohirofumi complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT okadayuta complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT matsuokyohei complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT hayashihironobu complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT saekiakinori complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT yamadahiroko complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals
AT arataninaoki complexationstudyofa13phenylenebridgedcyclichexanaphthalenewithfullerenesc60andc70insolutionand1dalignmentoffullerenesinthecrystals