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Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines
[Image: see text] The light-driven activation of halophosphines R(2)PX (R = alkyl- or aryl, X = Cl, Br) by an Ir(III)-based photocatalyst is described. It is shown that initially formed secondary phosphines R(2)PH react readily with the remaining R(2)PX in a parent–child reaction to form diphosphine...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647117/ https://www.ncbi.nlm.nih.gov/pubmed/37853683 http://dx.doi.org/10.1021/acs.inorgchem.3c01946 |