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Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N–N Bond Cleavage

[Image: see text] Diketiminate-supported iron complexes are capable of cleaving the strong triple bond of N(2) to give a tetra-iron complex with two nitrides (Rodriguez et al., Science, 2011, 334, 780–783). The mechanism of this reaction has been difficult to determine, but a transient green species...

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Detalles Bibliográficos
Autores principales: Wandzilak, Aleksandra, Grubel, Katarzyna, Skubi, Kazimer L., McWilliams, Sean F., Bessas, Dimitrios, Rana, Atanu, Hugenbruch, Stefan, Dey, Abhishek, Holland, Patrick L., DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647920/
https://www.ncbi.nlm.nih.gov/pubmed/37902987
http://dx.doi.org/10.1021/acs.inorgchem.3c02594