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Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N–N Bond Cleavage
[Image: see text] Diketiminate-supported iron complexes are capable of cleaving the strong triple bond of N(2) to give a tetra-iron complex with two nitrides (Rodriguez et al., Science, 2011, 334, 780–783). The mechanism of this reaction has been difficult to determine, but a transient green species...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647920/ https://www.ncbi.nlm.nih.gov/pubmed/37902987 http://dx.doi.org/10.1021/acs.inorgchem.3c02594 |