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Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials

In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity,...

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Detalles Bibliográficos
Autores principales: Wang, Xuming, Li, Xin, Wu, Qiang, Yuan, Yubin, Liu, Weihua, Han, Chuanyu, Wang, Xiaoli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648664/
https://www.ncbi.nlm.nih.gov/pubmed/37947716
http://dx.doi.org/10.3390/nano13212871
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author Wang, Xuming
Li, Xin
Wu, Qiang
Yuan, Yubin
Liu, Weihua
Han, Chuanyu
Wang, Xiaoli
author_facet Wang, Xuming
Li, Xin
Wu, Qiang
Yuan, Yubin
Liu, Weihua
Han, Chuanyu
Wang, Xiaoli
author_sort Wang, Xuming
collection PubMed
description In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity, and reaction speed. This paper presents a sensitive material and a surface acoustic gas sensor for detecting dimethyl methyl phosphonate. The results demonstrate that the sensor exhibits good selectivity and could detect 80 ppb of dimethyl methyl phosphonate within 1 min. As an integral component of the sensor, the microstructure and adsorption mechanism of silica molecular imprinting material were studied in detail. The results show that the template molecule could significantly affect the pore volume, specific surface area, and hydroxyl density of mesoporous materials. These properties further affect the performance of the sensor. This study provides a valuable case study for the design of sensitive materials.
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spelling pubmed-106486642023-10-30 Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials Wang, Xuming Li, Xin Wu, Qiang Yuan, Yubin Liu, Weihua Han, Chuanyu Wang, Xiaoli Nanomaterials (Basel) Article In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity, and reaction speed. This paper presents a sensitive material and a surface acoustic gas sensor for detecting dimethyl methyl phosphonate. The results demonstrate that the sensor exhibits good selectivity and could detect 80 ppb of dimethyl methyl phosphonate within 1 min. As an integral component of the sensor, the microstructure and adsorption mechanism of silica molecular imprinting material were studied in detail. The results show that the template molecule could significantly affect the pore volume, specific surface area, and hydroxyl density of mesoporous materials. These properties further affect the performance of the sensor. This study provides a valuable case study for the design of sensitive materials. MDPI 2023-10-30 /pmc/articles/PMC10648664/ /pubmed/37947716 http://dx.doi.org/10.3390/nano13212871 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Xuming
Li, Xin
Wu, Qiang
Yuan, Yubin
Liu, Weihua
Han, Chuanyu
Wang, Xiaoli
Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title_full Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title_fullStr Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title_full_unstemmed Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title_short Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
title_sort detection of dimethyl methyl phosphonate by silica molecularly imprinted materials
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648664/
https://www.ncbi.nlm.nih.gov/pubmed/37947716
http://dx.doi.org/10.3390/nano13212871
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