Cargando…
Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials
In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity,...
Autores principales: | , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648664/ https://www.ncbi.nlm.nih.gov/pubmed/37947716 http://dx.doi.org/10.3390/nano13212871 |
_version_ | 1785135391271026688 |
---|---|
author | Wang, Xuming Li, Xin Wu, Qiang Yuan, Yubin Liu, Weihua Han, Chuanyu Wang, Xiaoli |
author_facet | Wang, Xuming Li, Xin Wu, Qiang Yuan, Yubin Liu, Weihua Han, Chuanyu Wang, Xiaoli |
author_sort | Wang, Xuming |
collection | PubMed |
description | In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity, and reaction speed. This paper presents a sensitive material and a surface acoustic gas sensor for detecting dimethyl methyl phosphonate. The results demonstrate that the sensor exhibits good selectivity and could detect 80 ppb of dimethyl methyl phosphonate within 1 min. As an integral component of the sensor, the microstructure and adsorption mechanism of silica molecular imprinting material were studied in detail. The results show that the template molecule could significantly affect the pore volume, specific surface area, and hydroxyl density of mesoporous materials. These properties further affect the performance of the sensor. This study provides a valuable case study for the design of sensitive materials. |
format | Online Article Text |
id | pubmed-10648664 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-106486642023-10-30 Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials Wang, Xuming Li, Xin Wu, Qiang Yuan, Yubin Liu, Weihua Han, Chuanyu Wang, Xiaoli Nanomaterials (Basel) Article In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity, and reaction speed. This paper presents a sensitive material and a surface acoustic gas sensor for detecting dimethyl methyl phosphonate. The results demonstrate that the sensor exhibits good selectivity and could detect 80 ppb of dimethyl methyl phosphonate within 1 min. As an integral component of the sensor, the microstructure and adsorption mechanism of silica molecular imprinting material were studied in detail. The results show that the template molecule could significantly affect the pore volume, specific surface area, and hydroxyl density of mesoporous materials. These properties further affect the performance of the sensor. This study provides a valuable case study for the design of sensitive materials. MDPI 2023-10-30 /pmc/articles/PMC10648664/ /pubmed/37947716 http://dx.doi.org/10.3390/nano13212871 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Wang, Xuming Li, Xin Wu, Qiang Yuan, Yubin Liu, Weihua Han, Chuanyu Wang, Xiaoli Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title | Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title_full | Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title_fullStr | Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title_full_unstemmed | Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title_short | Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials |
title_sort | detection of dimethyl methyl phosphonate by silica molecularly imprinted materials |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648664/ https://www.ncbi.nlm.nih.gov/pubmed/37947716 http://dx.doi.org/10.3390/nano13212871 |
work_keys_str_mv | AT wangxuming detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT lixin detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT wuqiang detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT yuanyubin detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT liuweihua detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT hanchuanyu detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials AT wangxiaoli detectionofdimethylmethylphosphonatebysilicamolecularlyimprintedmaterials |