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Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries

After more than 30 years of delay compared to lithium-ion batteries, sodium analogs are now emerging in the market. This is a result of the concerns regarding sustainability and production costs of the former, as well as issues related to safety and toxicity. Electrode materials for the new sodium-i...

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Autores principales: Alcántara, Ricardo, Pérez-Vicente, Carlos, Lavela, Pedro, Tirado, José L., Medina, Alejandro, Stoyanova, Radostina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10649210/
https://www.ncbi.nlm.nih.gov/pubmed/37959567
http://dx.doi.org/10.3390/ma16216970
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author Alcántara, Ricardo
Pérez-Vicente, Carlos
Lavela, Pedro
Tirado, José L.
Medina, Alejandro
Stoyanova, Radostina
author_facet Alcántara, Ricardo
Pérez-Vicente, Carlos
Lavela, Pedro
Tirado, José L.
Medina, Alejandro
Stoyanova, Radostina
author_sort Alcántara, Ricardo
collection PubMed
description After more than 30 years of delay compared to lithium-ion batteries, sodium analogs are now emerging in the market. This is a result of the concerns regarding sustainability and production costs of the former, as well as issues related to safety and toxicity. Electrode materials for the new sodium-ion batteries may contain available and sustainable elements such as sodium itself, as well as iron or manganese, while eliminating the common cobalt cathode compounds and copper anode current collectors for lithium-ion batteries. The multiple oxidation states, abundance, and availability of manganese favor its use, as it was shown early on for primary batteries. Regarding structural considerations, an extraordinarily successful group of cathode materials are layered oxides of sodium, and transition metals, with manganese being the major component. However, other technologies point towards Prussian blue analogs, NASICON-related phosphates, and fluorophosphates. The role of manganese in these structural families and other oxide or halide compounds has until now not been fully explored. In this direction, the present review paper deals with the different Mn-containing solids with a non-layered structure already evaluated. The study aims to systematize the current knowledge on this topic and highlight new possibilities for further study, such as the concept of entatic state applied to electrodes.
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spelling pubmed-106492102023-10-30 Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries Alcántara, Ricardo Pérez-Vicente, Carlos Lavela, Pedro Tirado, José L. Medina, Alejandro Stoyanova, Radostina Materials (Basel) Review After more than 30 years of delay compared to lithium-ion batteries, sodium analogs are now emerging in the market. This is a result of the concerns regarding sustainability and production costs of the former, as well as issues related to safety and toxicity. Electrode materials for the new sodium-ion batteries may contain available and sustainable elements such as sodium itself, as well as iron or manganese, while eliminating the common cobalt cathode compounds and copper anode current collectors for lithium-ion batteries. The multiple oxidation states, abundance, and availability of manganese favor its use, as it was shown early on for primary batteries. Regarding structural considerations, an extraordinarily successful group of cathode materials are layered oxides of sodium, and transition metals, with manganese being the major component. However, other technologies point towards Prussian blue analogs, NASICON-related phosphates, and fluorophosphates. The role of manganese in these structural families and other oxide or halide compounds has until now not been fully explored. In this direction, the present review paper deals with the different Mn-containing solids with a non-layered structure already evaluated. The study aims to systematize the current knowledge on this topic and highlight new possibilities for further study, such as the concept of entatic state applied to electrodes. MDPI 2023-10-30 /pmc/articles/PMC10649210/ /pubmed/37959567 http://dx.doi.org/10.3390/ma16216970 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Alcántara, Ricardo
Pérez-Vicente, Carlos
Lavela, Pedro
Tirado, José L.
Medina, Alejandro
Stoyanova, Radostina
Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title_full Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title_fullStr Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title_full_unstemmed Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title_short Review and New Perspectives on Non-Layered Manganese Compounds as Electrode Material for Sodium-Ion Batteries
title_sort review and new perspectives on non-layered manganese compounds as electrode material for sodium-ion batteries
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10649210/
https://www.ncbi.nlm.nih.gov/pubmed/37959567
http://dx.doi.org/10.3390/ma16216970
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