Cargando…

Electrospun Manganese-Based Metal–Organic Frameworks for MnO(x) Nanostructures Embedded in Carbon Nanofibers as a High-Performance Nonenzymatic Glucose Sensor

[Image: see text] Material-specific electrocatalytic activity and electrode design are essential factors in evaluating the performance of electrochemical sensors. Herein, the technique described involves electrospinning manganese-based metal–organic frameworks (Mn-MOFs) to develop MnO(x) nanostructu...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, So Eun, Yoon, Jae Chol, Tae, Hyun-Jin, Muthurasu, Alagan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10652823/
https://www.ncbi.nlm.nih.gov/pubmed/38024713
http://dx.doi.org/10.1021/acsomega.3c05459
Descripción
Sumario:[Image: see text] Material-specific electrocatalytic activity and electrode design are essential factors in evaluating the performance of electrochemical sensors. Herein, the technique described involves electrospinning manganese-based metal–organic frameworks (Mn-MOFs) to develop MnO(x) nanostructures embedded in carbon nanofibers. The resulting structure features an electrocatalytic material for an enzyme-free glucose sensor. The elemental composition, morphology, and microstructure of the fabricated electrodes materials were characterized by using energy-dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Cyclic voltammetry (CV) and amperometric i–t (current–time) techniques are characteristically employed to assess the electrochemical performance of materials. The MOF MnO(x)-CNFs nanostructures significantly improve detection performance for nonenzymatic amperometric glucose sensors, including a broad linear range (0 mM to 9.1 mM), high sensitivity (4080.6 μA mM(–1) cm(–2)), a low detection limit (0.3 μM, S/N = 3), acceptable selectivity, outstanding reproducibility, and stability. The strategy of metal and metal oxide-integrated CNF nanostructures based on MOFs opens interesting possibilities for the development of high-performance electrochemical sensors.