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A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene
[Image: see text] Cp(2)Hf(CH(3))(2) reacts with silica containing strong aluminum Lewis sites to form Cp(2)Hf–(13)CH(3)(+) paired with aluminate anions. Solid-state NMR studies show that this reaction also forms neutral organohafnium and hafnium sites lacking methyl groups. Cp(2)Hf–(13)CH(3)(+) reac...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10655186/ https://www.ncbi.nlm.nih.gov/pubmed/37921588 http://dx.doi.org/10.1021/jacs.3c05940 |