Cargando…

Silver-Exchanged Zeolite Y Catalyzes a Selective Insertion of Carbenes into C–H and O–H Bonds

[Image: see text] Commercially available zeolite Y modulates the catalytic activity and selectivity of ultrasmall silver species during the Buchner reaction and the carbene addition to methylene and hydroxyl bonds, by simply exchanging the counter cations of the zeolite framework. The zeolite acts a...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zheng, Yongkun, Vidal-Moya, Alejandro, Hernández-Garrido, Juan Carlos, Mon, Marta, Leyva-Pérez, Antonio
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10655197/ https://www.ncbi.nlm.nih.gov/pubmed/37922487 http://dx.doi.org/10.1021/jacs.3c08317

Ejemplares similares

Isocyanate-Free Polyurea Synthesis via Ru-Catalyzed Carbene Insertion into the N–H Bonds of Urea
por: de Zwart, Felix J., et al.
Publicado: (2022)

Enantioselective carbene insertion into the N–H bond of benzophenone imine
por: Yang, Jian, et al.
Publicado: (2019)

Chemoselective carbene insertion into the N−H bonds of NH(3)·H(2)O
por: Liu, Zhaohong, et al.
Publicado: (2022)

Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C−C σ-Bonds of 1,3-Dicarbonyls
por: Liu, Zhaohong, et al.
Publicado: (2018)

Metal-free tandem carbene N–H insertions and C–C bond cleavages
por: Chen, Pu, et al.
Publicado: (2020)

Palladium-catalyzed intramolecular enantioselective C(sp(3))–H insertion of donor/donor carbenes
por: Li, Wendeng, et al.
Publicado: (2022)

Exporting Metal‐Carbene Chemistry to Live Mammalian Cells: Copper‐Catalyzed Intracellular Synthesis of Quinoxalines Enabled by N−H Carbene Insertions
por: Gutiérrez, Sara, et al.
Publicado: (2021)

Recent advances in C(sp(3))–H bond functionalization via metal–carbene insertions
por: Wang, Bo, et al.
Publicado: (2016)

Divergent stereochemical outcomes in the insertion of donor/donor carbenes into the C–H bonds of stereogenic centers
por: Dishman, Sarah N., et al.
Publicado: (2021)

Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene
por: Philipp, Michael S. M., et al.
Publicado: (2022)

Migratory Insertion of Carbenes into Au(III)–C Bonds
por: Zhukhovitskiy, Aleksandr V., et al.
Publicado: (2017)

X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal–Organic Cage with Alkynes as Safe Carbene Precursors
por: Chen, Lianfen, et al.
Publicado: (2023)

C-H Functionalization via Iron-Catalyzed Carbene-Transfer Reactions
por: Empel, Claire, et al.
Publicado: (2020)

Silver-Free Gold-Catalyzed Heterocyclizations through Intermolecular H-Bonding Activation
por: Elías-Rodríguez, Pilar, et al.
Publicado: (2023)

Enantioselective Synthesis of α-Trifluoromethyl Amines via Biocatalytic N–H Bond Insertion with Acceptor-Acceptor Carbene Donors
por: Nam, Donggeon, et al.
Publicado: (2022)

Intermolecular carbene S–H insertion catalysed by engineered myoglobin-based catalysts
por: Tyagi, Vikas, et al.
Publicado: (2015)

Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
por: Ortega-Arizmendi, Aldo I., et al.
Publicado: (2013)

Iridium/N-heterocyclic carbene-catalyzed C–H borylation of arenes by diisopropylaminoborane
por: Tobisu, Mamoru, et al.
Publicado: (2016)

Rhodium‐Catalyzed C−H Methylation and Alkylation Reactions by Carbene‐Transfer Reactions
por: Empel, Claire, et al.
Publicado: (2022)

Intramolecular Carbene C-H Insertion Reactions of 2-Diazo-2-sulfamoylacetamides
por: Que, Chuqiang, et al.
Publicado: (2019)

Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes
por: Nickerson, Leslie A., et al.
Publicado: (2019)

Insertion of Carbenes into Deprotonated nido-Undecaborane, B(11)H(13)(2-)
por: Pecyna, Jacek, et al.
Publicado: (2019)

Adsorption of radon on silver exchanged zeolites at ambient temperatures
por: Heinitz, Stephan, et al.
Publicado: (2023)

Silver Catalyzed Site-Selective C(sp(3))−H Bond Amination of Secondary over Primary C(sp(3))−H Bonds
por: Jiao, Luzhen, et al.
Publicado: (2022)

Is silver a mere terminal oxidant in palladium catalyzed C–H bond activation reactions?
por: Bhaskararao, Bangaru, et al.
Publicado: (2019)

Facile H/D Exchange at (Hetero)Aromatic Hydrocarbons Catalyzed by a Stable Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex
por: Garhwal, Subhash, et al.
Publicado: (2020)

Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes
por: Nickerson, Leslie A., et al.
Publicado: (2020)

Rh(iii)-catalyzed regioselective intermolecular N-methylene Csp(3)–H bond carbenoid insertion
por: Xie, Haisheng, et al.
Publicado: (2017)

High-Pressure Insertion of Dense H(2) into a Model Zeolite
por: Xu, Wan, et al.
Publicado: (2021)

Uncommon carbene insertion reactions
por: Huang, Ming-Yao, et al.
Publicado: (2021)

Hybrid catalysts based on N-heterocyclic carbene anchored on hierarchical zeolites
por: Gianotti, Enrica, et al.
Publicado: (2019)

Critical Admission Temperature of H(2) and CH(4) in Nanopores of Exchanged ERI Zeolites
por: Quiroz-Estrada, Karla, et al.
Publicado: (2019)

From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp(3))–H Bond
por: Chi, Huiwen, et al.
Publicado: (2019)

Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction
por: Zhang, Guan, et al.
Publicado: (2022)

Modular Synthesis of Highly Substituted 3-Azapyrroles by Rh(II)-Catalyzed N–H Bond Insertion and Cyclodehydration
por: Williams, Matthew B., et al.
Publicado: (2022)

Artificial Metalloenzyme-Catalyzed Enantioselective Amidation via Nitrene Insertion in Unactivated C(sp(3))–H Bonds
por: Yu, Kun, et al.
Publicado: (2023)

Multi C−H Functionalization Reactions of Carbazole Heterocycles via Gold‐Catalyzed Carbene Transfer Reactions
por: Jana, Sripati, et al.
Publicado: (2021)

Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp(3))−H Bond Insertion
por: Díaz‐Jiménez, Àlex, et al.
Publicado: (2022)

Synthesis of Di-, Tri-, and Tetrasubstituted Oxetanes by Rhodium-Catalyzed O=H Insertion and C=C Bond-Forming Cyclization**
por: Davis, Owen A, et al.
Publicado: (2014)

Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C−H Insertion, and Dimerization Reactions
por: García‐Morales, Cristina, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_egvdc4uffcronc37bs4k7dnlu6