Cargando…

A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene

Due to their intrinsic high reactivity, isolation of tin(0) complexes remains challenging. Herein, we report the synthesis of a silylene-stabilized ditin(0) complex (2) by reduction of a silylene-supported dibromostannylene (1) with 1 equivalent of magnesium (I) dimer in toluene. The structure of 2...

Descripción completa

Detalles Bibliográficos
Autores principales:	Du, Shaozhi, Cao, Fanshu, Chen, Xi, Rong, Hua, Song, Haibin, Mo, Zhenbo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10656547/ https://www.ncbi.nlm.nih.gov/pubmed/37978294 http://dx.doi.org/10.1038/s41467-023-42953-5

Ejemplares similares

Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations
por: Wang, Xuyang, et al.
Publicado: (2023)

A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment
por: Frutos, María, et al.
Publicado: (2022)

Bis(silylene)‐Stabilized Monovalent Nitrogen Complexes
por: Yao, Shenglai, et al.
Publicado: (2020)

Reversible Isomerization Between Silacyclopropyl Cation and Cyclic (Alkyl)(Amino)Silylene
por: Nougué, Raphaël, et al.
Publicado: (2022)

Tetrachloridodi-μ(3)-oxido-tetrakis(μ(2)-propan-2-olato-κ(2) O:O)ditin(II)ditin(IV)
por: Yarushnikov, Oleg, et al.
Publicado: (2014)

Stimuli Responsive Silylene: Electromerism Induced Reversible Switching Between Mono‐ and Bis‐Silylene
por: Yadav, Ravi, et al.
Publicado: (2022)

Synthesis and Characterization of Block Copolymers of Poly(silylene diethynylbenzen) and Poly(silylene dipropargyl aryl ether)
por: Gao, Man, et al.
Publicado: (2021)

Poly[[aquadi-μ(3)-malonato-hexaphenylditin(IV)] acetone solvate]
por: Win, Yip Foo, et al.
Publicado: (2010)

DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds
por: Holzner, Richard, et al.
Publicado: (2020)

Stabilization of Reactive Nitrene by Silylenes without Using a Reducing Metal
por: Ding, Yi, et al.
Publicado: (2021)

Potassium ditin(IV) tris[phosphate(V)], KSn(2)(PO(4))(3)
por: Zhang, Hui Ju
Publicado: (2011)

Generation of Bis(ferrocenyl)silylenes from Siliranes †
por: Pan, Yang, et al.
Publicado: (2020)

Synthesis and Reactivity of a Neutral Homocyclic Silylene
por: Keuter, Jan, et al.
Publicado: (2021)

Poly[tetrabutyltetrakis(μ(2)-hydrogen phenylphosphonato)ditin(IV)]
por: Sarr, Modou, et al.
Publicado: (2012)

Bis{decacarbonylbis[μ-2,2′-(phenylimino)diethanolato]ditin(II)ditungsten(0)(2 Sn—W)} hexacarbonyltungsten(0)
por: Berends, Thorsten, et al.
Publicado: (2010)

Small Molecule Activation by Two‐Coordinate Acyclic Silylenes
por: Fujimori, Shiori, et al.
Publicado: (2020)

Interconversion and reactivity of manganese silyl, silylene, and silene complexes
por: Price, Jeffrey S., et al.
Publicado: (2019)

Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C(1)-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes
por: Wang, Huajin, et al.
Publicado: (2018)

A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand
por: Xu, Jian, et al.
Publicado: (2021)

Synthesis and Reactivity of Bis(silylene)‐Coordinated Calcium and Divalent Lanthanide Complexes
por: Sun, Xiaofei, et al.
Publicado: (2020)

Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens
por: Sinhababu, Soumen, et al.
Publicado: (2019)

A Stable N‐Heterocyclic Silylene with a 1,1′‐Ferrocenediyl Backbone
por: Weyer, Nadine, et al.
Publicado: (2020)

Modelling the non-local thermodynamic equilibrium spectra of silylene (SiH(2))
por: Clark, Victoria H. J., et al.
Publicado: (2021)

A cyclopentadienyl functionalized silylene – a flexible ligand for Si- and C-coordination
por: Kaufmann, Sebastian, et al.
Publicado: (2020)

A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene)
por: Luecke, Marcel‐Philip, et al.
Publicado: (2021)

A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d(7)-Mn(CO)(5) radical
por: Kalra, Shweta, et al.
Publicado: (2022)

Synthesis and Coordination Behavior of a New Hybrid Bidentate Ligand with Phosphine and Silylene Donors
por: Nazish, Mohd, et al.
Publicado: (2020)

Metalation-induced denitrogenative reductive coupling of isocyanides on a silylene-bridged nickel cluster
por: Shimamoto, Kento, et al.
Publicado: (2022)

Bipolar and Unipolar Silylene-Diphenylene σ-π Conjugated Polymer Route for Highly Efficient Electrophosphorescence
por: Chang, Yao-Tang, et al.
Publicado: (2016)

Taming a monomeric [Cu(η(6)-C(6)H(6))](+) complex with silylene
por: Parvin, Nasrina, et al.
Publicado: (2018)

N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence
por: Krahfuß, Mirjam J., et al.
Publicado: (2020)

Reactivity of a Unique Si(I)–Si(I)-Based η(2)-Bis(silylene) Iron Complex
por: He, Zhiyuan, et al.
Publicado: (2022)

Open-Shell Lanthanide(II+) or -(III+) Complexes Bearing σ-Silyl and Silylene Ligands: Synthesis, Structure, and Bonding Analysis
por: Zitz, Rainer, et al.
Publicado: (2015)

Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation
por: Hadlington, Terrance J., et al.
Publicado: (2020)

Effect of backbone conformation and its defects on electronic properties and assessment of the stabilizing role of π–π interactions in aryl substituted polysilylenes studied by DFT on deca[methyl(phenyl)silylene]s
por: Hanulikova, Barbora, et al.
Publicado: (2016)

Unexpected White Phosphorus (P(4)) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene
por: Xiong, Yun, et al.
Publicado: (2022)

Stabilization of 2,6-Diarylanilinum Cation by Through-Space Cation−π Interactions
por: Simó Padial, Joan, et al.
Publicado: (2017)

A [CoSiH(2)] Silylene Synthon Provides Modular Access to Homo- and Heterobimetallic [Co=Si=M] (M = Co, Fe) Silicide Complexes
por: Handford, Rex C., et al.
Publicado: (2023)

Zwitterionic-to-cationic charge conversion polyprodrug nanomedicine for enhanced drug delivery
por: Wang, Sheng, et al.
Publicado: (2020)

Differential stabilization of adenine quartets by anions and cations
por: van der Wijst, Tushar, et al.
Publicado: (2009)

Cannot write session to /tmp/vufind_sessions/sess_eebhm0ss424otpqv7616635uen