Highly porous and rough polydimethylsiloxane film-based triboelectric nanogenerators and its application for electrochemical cathodic protection

The development and utilization of triboelectric nanogenerator (TENG) are very important for realizing energy cleaning in electrochemical processes. However, limited electrical output performance plays a major stumbling block to this process. Herein, a porous and high-roughness PDMS (PR/PDMS) negative friction layer was obtained by doping PDMS with powdered chitosan and casting using a sacrificial anodic alumina template. A TENG was fabricated by the PR/PDMS with Al film (PR-TENG). The PR-TENG exhibited much better performance than the pure PDMS-based TENG, which was attributed to the porous properties of the PR/PDMS. Under the driving of external mechanical force at 5 Hz, the PR-TENG showed a maximum output open-circuit voltage (V(oc)) and short-circuit current density (J(sc)) of 77.1 V and 33.9 mA/m(2), respectively. To prove the concept, the electrochemical cathodic protection system with PR-TENG was constructed. Ultimately, the application prospects of the PR-TENG as a clean energy source for electrochemical processes were explored and evaluated.