Synthesis of Large Macrocycles with Chiral Sulfur Centers via Enantiospecific SuFEx and SuPhenEx Click Reactions

[Image: see text] Here we report the first asymmetric synthesis of large chiral macrocycles with chiral sulfur atoms. Building on stereospecific SuFEx and SuPhenEx click chemistries, this approach utilizes disulfonimidoyl fluorides and disulfonimidoyl p-nitrophenolates—which are efficient building b...

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Detalles Bibliográficos
Autores principales: Chao, Yang, Subramaniam, Muthusamy, Namitharan, Kayambu, Zhu, Yumei, Koolma, Victor, Hao, Zitong, Li, Shikang, Wang, Yaxin, Hudoynazarov, Ilyos, Miloserdov, Fedor M., Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10660663/
https://www.ncbi.nlm.nih.gov/pubmed/37903243
http://dx.doi.org/10.1021/acs.joc.3c01656

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