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Mechanistic Insights into the DABCO-Catalyzed Cloke–Wilson Rearrangement: A DFT Perspective

[Image: see text] The mechanism and selectivity patterns of the DABCO-catalyzed Cloke–Wilson rearrangement were computationally studied in detail using density functional theory calculations. Our computations suggest that the process occurs stepwise involving the initial ring opening of the cyclopro...

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Detalles Bibliográficos
Autores principales:	Gallardo-Fuentes, Sebastián, Lodeiro, Lucas, Matute, Ricardo, Fernández, Israel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10661052/ https://www.ncbi.nlm.nih.gov/pubmed/37885222 http://dx.doi.org/10.1021/acs.joc.3c02011

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