Optimal pretreatment of plantain peel waste valorization for biogas production: Insights into neural network modeling and kinetic analysis

This work proposed a model for the substrate treatment stage of biogas production process in an anaerobic digestion system. Adaptive neuro-fuzzy inference system (ANFIS), response surface method (RSM), and artificial neural network (ANN) were comparatively used in the simulation and modeling of the treatment process for improved biogas yield. Waste plantain peels were pretreated and used as substrate. FTIR and SEM results revealed that the pretreatment improved the substrate's desirable qualities. The amount of biogas yield was controlled by time, NaOH concentration, and temperature of the substrate pretreatment. Optimum pretreatment conditions obtained were a temperature of 102.7 °C, time of 31.7 min and NaOH concentration of 0.125 N. RSM, ANN, and ANFIS modeling techniques were proficient in simulating the biogas production, as evidenced by high R(2)values of 0.9281, 0.9850, and 0.9852, respectively. Furthermore, the values of the calculated error terms such as RMSE (RSM = 0.04799, ANN = 0.00969, and ANFIS = 0.00587) and HYBRID (RSM = 18.556, ANN = 0.803, and ANFIS = 0.0447) were low, indicating a satisfactory correlation between experimental and predicted values. Scrubbing of the biogas with caustic soda and activated charcoal increased the methane content to 94 %. The kinetics of the cumulative biogas yield were best fit with the Logistics and Modified Logistics models. The low C/N ratio in addition to the presence of potassium, nitrogen, and phosphorus suggested that the spent plantain peel slurry can be utilized as an agricultural fertilizer in crop production. The observations of this study therefore recommends the pre-treatment of biodigestion substrates as a key means to enhance beneficiation of methane production.