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An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries
Ni-rich cathode materials suffer from rapid capacity fading caused by interface side reactions and bulk structure degradation. Previous studies show that Co is conducive to bulk structure stability and sulfate can react with the residual lithium (LiOH and Li(2)CO(3)) on the surface of Ni-rich cathod...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664004/ https://www.ncbi.nlm.nih.gov/pubmed/38020016 http://dx.doi.org/10.1039/d3ra04145j |
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author | Zhou, Jingjing Wei, Bingxin Liu, Meng Qin, Yinping Cheng, Hongyu Lyu, Yingchun Liu, Yang Guo, Bingkun |
author_facet | Zhou, Jingjing Wei, Bingxin Liu, Meng Qin, Yinping Cheng, Hongyu Lyu, Yingchun Liu, Yang Guo, Bingkun |
author_sort | Zhou, Jingjing |
collection | PubMed |
description | Ni-rich cathode materials suffer from rapid capacity fading caused by interface side reactions and bulk structure degradation. Previous studies show that Co is conducive to bulk structure stability and sulfate can react with the residual lithium (LiOH and Li(2)CO(3)) on the surface of Ni-rich cathode materials and form a uniform coating to suppress the side reactions between the cathode and electrolyte. Here, CoSO(4) is utilized as a modifier for LiNi(0.8)Co(0.1)Mn(0.1)O(2) (NCM811) cathode materials. It reacts with the residual lithium on the surface of the NCM811 cathode to form Li-ion conductive Li(2)SO(4) protective layers and Co doping simultaneously during the high-temperature sintering process, which can suppress the side reactions between the Ni-rich cathode and electrolyte and effectively prevent the structural transformation. As a result, the co-modified NCM811 cathode with 3 wt% CoSO(4) exhibits an improved cycling performance of 81.1% capacity retention after 200 cycles at 1C and delivers an excellent rate performance at 5C of 187.4 mA h g(−1), which is 10.2% higher than that of the pristine NCM811 cathode. |
format | Online Article Text |
id | pubmed-10664004 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-106640042023-11-22 An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries Zhou, Jingjing Wei, Bingxin Liu, Meng Qin, Yinping Cheng, Hongyu Lyu, Yingchun Liu, Yang Guo, Bingkun RSC Adv Chemistry Ni-rich cathode materials suffer from rapid capacity fading caused by interface side reactions and bulk structure degradation. Previous studies show that Co is conducive to bulk structure stability and sulfate can react with the residual lithium (LiOH and Li(2)CO(3)) on the surface of Ni-rich cathode materials and form a uniform coating to suppress the side reactions between the cathode and electrolyte. Here, CoSO(4) is utilized as a modifier for LiNi(0.8)Co(0.1)Mn(0.1)O(2) (NCM811) cathode materials. It reacts with the residual lithium on the surface of the NCM811 cathode to form Li-ion conductive Li(2)SO(4) protective layers and Co doping simultaneously during the high-temperature sintering process, which can suppress the side reactions between the Ni-rich cathode and electrolyte and effectively prevent the structural transformation. As a result, the co-modified NCM811 cathode with 3 wt% CoSO(4) exhibits an improved cycling performance of 81.1% capacity retention after 200 cycles at 1C and delivers an excellent rate performance at 5C of 187.4 mA h g(−1), which is 10.2% higher than that of the pristine NCM811 cathode. The Royal Society of Chemistry 2023-11-22 /pmc/articles/PMC10664004/ /pubmed/38020016 http://dx.doi.org/10.1039/d3ra04145j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Zhou, Jingjing Wei, Bingxin Liu, Meng Qin, Yinping Cheng, Hongyu Lyu, Yingchun Liu, Yang Guo, Bingkun An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title | An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title_full | An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title_fullStr | An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title_full_unstemmed | An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title_short | An effective co-modification strategy to enhance the cycle stability of LiNi(0.8)Co(0.1)Mn(0.1)O(2) for lithium-ion batteries |
title_sort | effective co-modification strategy to enhance the cycle stability of lini(0.8)co(0.1)mn(0.1)o(2) for lithium-ion batteries |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664004/ https://www.ncbi.nlm.nih.gov/pubmed/38020016 http://dx.doi.org/10.1039/d3ra04145j |
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