Gold-catalyzed alkenylation and arylation of phosphorothioates

Reported herein is the ligand-enabled gold-catalyzed alkenylation and arylation of phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial role of the in situ generated Ag–sulfur complex, which undergoes a facile transmetalation with the Au(iii) intermediate, thereby...

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Detalles Bibliográficos
Autores principales: Urvashi, Mishra, Sampoorna, Patil, Nitin T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664589/
https://www.ncbi.nlm.nih.gov/pubmed/38023501
http://dx.doi.org/10.1039/d3sc04888h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664589/
https://www.ncbi.nlm.nih.gov/pubmed/38023501
http://dx.doi.org/10.1039/d3sc04888h

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