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Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation

This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESE...

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Detalles Bibliográficos
Autores principales: Jin Lee, Dong, Mohan Kumar, Ganesan, Sekar, Sankar, Chang Jeon, Hee, Young Kim, Deuk, Ilanchezhiyan, Pugazhendi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10665665/
https://www.ncbi.nlm.nih.gov/pubmed/37952468
http://dx.doi.org/10.1016/j.ultsonch.2023.106681
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author Jin Lee, Dong
Mohan Kumar, Ganesan
Sekar, Sankar
Chang Jeon, Hee
Young Kim, Deuk
Ilanchezhiyan, Pugazhendi
author_facet Jin Lee, Dong
Mohan Kumar, Ganesan
Sekar, Sankar
Chang Jeon, Hee
Young Kim, Deuk
Ilanchezhiyan, Pugazhendi
author_sort Jin Lee, Dong
collection PubMed
description This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV–Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO(3)/Ti(3)C(2) was superior to that of bare WO(3), with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO(3). The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO(3)/Ti(3)C(2) heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti(3)C(2)′s active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen.
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spelling pubmed-106656652023-11-07 Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation Jin Lee, Dong Mohan Kumar, Ganesan Sekar, Sankar Chang Jeon, Hee Young Kim, Deuk Ilanchezhiyan, Pugazhendi Ultrason Sonochem Ultrasonic Degradation of Pollutant This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV–Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO(3)/Ti(3)C(2) was superior to that of bare WO(3), with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO(3). The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO(3)/Ti(3)C(2) heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti(3)C(2)′s active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen. Elsevier 2023-11-07 /pmc/articles/PMC10665665/ /pubmed/37952468 http://dx.doi.org/10.1016/j.ultsonch.2023.106681 Text en © 2023 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ultrasonic Degradation of Pollutant
Jin Lee, Dong
Mohan Kumar, Ganesan
Sekar, Sankar
Chang Jeon, Hee
Young Kim, Deuk
Ilanchezhiyan, Pugazhendi
Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title_full Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title_fullStr Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title_full_unstemmed Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title_short Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
title_sort ultrasonic processing of wo(3) nanosheets integrated ti(3)c(2) mxene 2d-2d based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
topic Ultrasonic Degradation of Pollutant
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10665665/
https://www.ncbi.nlm.nih.gov/pubmed/37952468
http://dx.doi.org/10.1016/j.ultsonch.2023.106681
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