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Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation
This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESE...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10665665/ https://www.ncbi.nlm.nih.gov/pubmed/37952468 http://dx.doi.org/10.1016/j.ultsonch.2023.106681 |
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author | Jin Lee, Dong Mohan Kumar, Ganesan Sekar, Sankar Chang Jeon, Hee Young Kim, Deuk Ilanchezhiyan, Pugazhendi |
author_facet | Jin Lee, Dong Mohan Kumar, Ganesan Sekar, Sankar Chang Jeon, Hee Young Kim, Deuk Ilanchezhiyan, Pugazhendi |
author_sort | Jin Lee, Dong |
collection | PubMed |
description | This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV–Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO(3)/Ti(3)C(2) was superior to that of bare WO(3), with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO(3). The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO(3)/Ti(3)C(2) heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti(3)C(2)′s active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen. |
format | Online Article Text |
id | pubmed-10665665 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-106656652023-11-07 Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation Jin Lee, Dong Mohan Kumar, Ganesan Sekar, Sankar Chang Jeon, Hee Young Kim, Deuk Ilanchezhiyan, Pugazhendi Ultrason Sonochem Ultrasonic Degradation of Pollutant This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV–Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO(3)/Ti(3)C(2) was superior to that of bare WO(3), with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO(3). The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO(3)/Ti(3)C(2) heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti(3)C(2)′s active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen. Elsevier 2023-11-07 /pmc/articles/PMC10665665/ /pubmed/37952468 http://dx.doi.org/10.1016/j.ultsonch.2023.106681 Text en © 2023 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Ultrasonic Degradation of Pollutant Jin Lee, Dong Mohan Kumar, Ganesan Sekar, Sankar Chang Jeon, Hee Young Kim, Deuk Ilanchezhiyan, Pugazhendi Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title | Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title_full | Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title_fullStr | Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title_full_unstemmed | Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title_short | Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
title_sort | ultrasonic processing of wo(3) nanosheets integrated ti(3)c(2) mxene 2d-2d based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation |
topic | Ultrasonic Degradation of Pollutant |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10665665/ https://www.ncbi.nlm.nih.gov/pubmed/37952468 http://dx.doi.org/10.1016/j.ultsonch.2023.106681 |
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