Alkyl Substituent in Heterocyclic Substrate, Carbon Skeleton Length of O-Nucleophilic Agent and Conditions Influence the Product Composition from Competitive Reactions of S(N)(ipso) Substitution by Aliphatic Oligoethers

Using (1)H NMR spectroscopy, we studied the relative mobility of the NO(2) group in 1-alkyl-5-nitro-1,2,4-triazoles in the reaction of nucleophilic heterocyclic substitution by aliphatic oligoethers. The main pathways of the S(N)(ipso) substitution process and the composition of resultant products f...

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Autores principales: Bosov, Konstantin K., Pivovarova, Ekaterina V., Krupnova, Irina A., Sukhanov, Gennady T., Sukhanova, Anna G., Filippova, Yulia V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10672302/
https://www.ncbi.nlm.nih.gov/pubmed/38004998
http://dx.doi.org/10.3390/ma16227068

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