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Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents

Latent fingerprints are a significant carrier of information for a court expert. To detect this type of forensic trace, what is necessary is a method that is easy to use, compact, and versatile. The research aimed to investigate the physicochemical properties of luminescent substances of donor–π–acc...

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Autores principales: Filipek, Patrycja, Hellwig, Hubert, Szlapa-Kula, Agata, Filapek, Michał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10674358/
https://www.ncbi.nlm.nih.gov/pubmed/38005318
http://dx.doi.org/10.3390/molecules28227597
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author Filipek, Patrycja
Hellwig, Hubert
Szlapa-Kula, Agata
Filapek, Michał
author_facet Filipek, Patrycja
Hellwig, Hubert
Szlapa-Kula, Agata
Filapek, Michał
author_sort Filipek, Patrycja
collection PubMed
description Latent fingerprints are a significant carrier of information for a court expert. To detect this type of forensic trace, what is necessary is a method that is easy to use, compact, and versatile. The research aimed to investigate the physicochemical properties of luminescent substances of donor–π–acceptor systems in terms of their potential use in detecting hidden fingerprints. During the research, a group of fluorene compounds consisting of the (-CH=C(CN)(COOR)) moiety was designed and successfully synthesized. The optical, electrochemical, and aggregation-induced emission properties were studied. The aggregation-induced emission of compounds has been studied in the mixture of THF (as a good solvent) and water (as a poor solvent) with different water fractions ranging from 0% to 99%. Due to the molecular structure, substances showed different affinities to organic traces. As a result, it was noticed that all compounds showed the AIE phenomenon, while during tests on latent fingerprints, it was observed that two substances had particularly forward-looking features in this field.
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spelling pubmed-106743582023-11-14 Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents Filipek, Patrycja Hellwig, Hubert Szlapa-Kula, Agata Filapek, Michał Molecules Article Latent fingerprints are a significant carrier of information for a court expert. To detect this type of forensic trace, what is necessary is a method that is easy to use, compact, and versatile. The research aimed to investigate the physicochemical properties of luminescent substances of donor–π–acceptor systems in terms of their potential use in detecting hidden fingerprints. During the research, a group of fluorene compounds consisting of the (-CH=C(CN)(COOR)) moiety was designed and successfully synthesized. The optical, electrochemical, and aggregation-induced emission properties were studied. The aggregation-induced emission of compounds has been studied in the mixture of THF (as a good solvent) and water (as a poor solvent) with different water fractions ranging from 0% to 99%. Due to the molecular structure, substances showed different affinities to organic traces. As a result, it was noticed that all compounds showed the AIE phenomenon, while during tests on latent fingerprints, it was observed that two substances had particularly forward-looking features in this field. MDPI 2023-11-14 /pmc/articles/PMC10674358/ /pubmed/38005318 http://dx.doi.org/10.3390/molecules28227597 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Filipek, Patrycja
Hellwig, Hubert
Szlapa-Kula, Agata
Filapek, Michał
Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title_full Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title_fullStr Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title_full_unstemmed Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title_short Simple Donor–π–Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
title_sort simple donor–π–acceptor compounds exhibiting aggregation-induced emission as hidden fingerprints detecting agents
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10674358/
https://www.ncbi.nlm.nih.gov/pubmed/38005318
http://dx.doi.org/10.3390/molecules28227597
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