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Can an Amine Be a Weaker and a Stronger Base at the Same Time? Curious Cases of Chameleonic Ionization
[Image: see text] We discovered an anomalous basic dissociation in certain multiprotic compounds. An amine group placed in the middle of a given compound is predicted to behave unusually—at certain pH ranges, its averaged degree of protonation actually increases with pH (!) resulting from interactio...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10683473/ https://www.ncbi.nlm.nih.gov/pubmed/38034037 http://dx.doi.org/10.1021/acsphyschemau.3c00029 |