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High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation

In this study, by doping the iridium (III) double ((4,6-difluorobenzene) -pyridine-N, C(2’)Pyridinformate (FIrpic) into 4,4′, 4″ three (carbazole) trioxilamine (TcTa) and 9 (4 tert-butyl-benzene) −3,6 double (triphenylsilyl) -9H carbazole (CzSi) layers as light emitting layers (EMLs) to achieve sky...

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Detalles Bibliográficos
Autores principales: Zhu, Qi, Xu, Jinglin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10687233/
https://www.ncbi.nlm.nih.gov/pubmed/38034767
http://dx.doi.org/10.1016/j.heliyon.2023.e22428
Descripción
Sumario:In this study, by doping the iridium (III) double ((4,6-difluorobenzene) -pyridine-N, C(2’)Pyridinformate (FIrpic) into 4,4′, 4″ three (carbazole) trioxilamine (TcTa) and 9 (4 tert-butyl-benzene) −3,6 double (triphenylsilyl) -9H carbazole (CzSi) layers as light emitting layers (EMLs) to achieve sky blue phosphor organic electroluminescence (EL) devices with very low efficiency roll-off. The dependence of the EL performance on the doping concentration of the light-emitting molecules and the different EML thicknesses are studied in detail. Experimental data show that the thin-film-doped TcTa layer is very important for the efficiency of the device. Finally, the optimal device achieves extremely high power efficiency, current efficiency, and external quantum efficiency (EQE), reaching 74.82 lm/W, 66.68 cd/A, and 31.9 %, respectively. At a certain luminance of 2000 cd/m(2) (3.4 V), the same device retained power efficiency with current efficiency and external quantum efficiency of 57.71 lm/W, 62.46 cd/A and 29.3 %, respectively, based on theoretical discussion, the improved EL efficiency was attributed to the energy levels of the host and luminescent molecules, which helps to balance the charge carrier in the emitter molecule distribution and expand the recombination region.