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High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation

In this study, by doping the iridium (III) double ((4,6-difluorobenzene) -pyridine-N, C(2’)Pyridinformate (FIrpic) into 4,4′, 4″ three (carbazole) trioxilamine (TcTa) and 9 (4 tert-butyl-benzene) −3,6 double (triphenylsilyl) -9H carbazole (CzSi) layers as light emitting layers (EMLs) to achieve sky...

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Detalles Bibliográficos
Autores principales: Zhu, Qi, Xu, Jinglin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10687233/
https://www.ncbi.nlm.nih.gov/pubmed/38034767
http://dx.doi.org/10.1016/j.heliyon.2023.e22428
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author Zhu, Qi
Xu, Jinglin
author_facet Zhu, Qi
Xu, Jinglin
author_sort Zhu, Qi
collection PubMed
description In this study, by doping the iridium (III) double ((4,6-difluorobenzene) -pyridine-N, C(2’)Pyridinformate (FIrpic) into 4,4′, 4″ three (carbazole) trioxilamine (TcTa) and 9 (4 tert-butyl-benzene) −3,6 double (triphenylsilyl) -9H carbazole (CzSi) layers as light emitting layers (EMLs) to achieve sky blue phosphor organic electroluminescence (EL) devices with very low efficiency roll-off. The dependence of the EL performance on the doping concentration of the light-emitting molecules and the different EML thicknesses are studied in detail. Experimental data show that the thin-film-doped TcTa layer is very important for the efficiency of the device. Finally, the optimal device achieves extremely high power efficiency, current efficiency, and external quantum efficiency (EQE), reaching 74.82 lm/W, 66.68 cd/A, and 31.9 %, respectively. At a certain luminance of 2000 cd/m(2) (3.4 V), the same device retained power efficiency with current efficiency and external quantum efficiency of 57.71 lm/W, 62.46 cd/A and 29.3 %, respectively, based on theoretical discussion, the improved EL efficiency was attributed to the energy levels of the host and luminescent molecules, which helps to balance the charge carrier in the emitter molecule distribution and expand the recombination region.
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spelling pubmed-106872332023-11-30 High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation Zhu, Qi Xu, Jinglin Heliyon Research Article In this study, by doping the iridium (III) double ((4,6-difluorobenzene) -pyridine-N, C(2’)Pyridinformate (FIrpic) into 4,4′, 4″ three (carbazole) trioxilamine (TcTa) and 9 (4 tert-butyl-benzene) −3,6 double (triphenylsilyl) -9H carbazole (CzSi) layers as light emitting layers (EMLs) to achieve sky blue phosphor organic electroluminescence (EL) devices with very low efficiency roll-off. The dependence of the EL performance on the doping concentration of the light-emitting molecules and the different EML thicknesses are studied in detail. Experimental data show that the thin-film-doped TcTa layer is very important for the efficiency of the device. Finally, the optimal device achieves extremely high power efficiency, current efficiency, and external quantum efficiency (EQE), reaching 74.82 lm/W, 66.68 cd/A, and 31.9 %, respectively. At a certain luminance of 2000 cd/m(2) (3.4 V), the same device retained power efficiency with current efficiency and external quantum efficiency of 57.71 lm/W, 62.46 cd/A and 29.3 %, respectively, based on theoretical discussion, the improved EL efficiency was attributed to the energy levels of the host and luminescent molecules, which helps to balance the charge carrier in the emitter molecule distribution and expand the recombination region. Elsevier 2023-11-19 /pmc/articles/PMC10687233/ /pubmed/38034767 http://dx.doi.org/10.1016/j.heliyon.2023.e22428 Text en https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Zhu, Qi
Xu, Jinglin
High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title_full High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title_fullStr High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title_full_unstemmed High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title_short High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
title_sort high efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10687233/
https://www.ncbi.nlm.nih.gov/pubmed/38034767
http://dx.doi.org/10.1016/j.heliyon.2023.e22428
work_keys_str_mv AT zhuqi highefficiencydoublelightemittinglayerskybluephosphororganiclightemittingdiodewithslowemissionefficiencyattenuation
AT xujinglin highefficiencydoublelightemittinglayerskybluephosphororganiclightemittingdiodewithslowemissionefficiencyattenuation