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Do Ionic Liquids Slow Down in Stages?

[Image: see text] High impact recent articles have reported on the existence of a liquid–liquid (L–L) phase transition as a function of both pressure and temperature in ionic liquids (ILs) containing the popular trihexyltetradecylphosphonium cation (P(666,14)(+)), sometimes referred to as the “unive...

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Detalles Bibliográficos
Autores principales: Borah, Bichitra, Acharya, Gobin Raj, Grajeda, Diana, Emerson, Matthew S., Harris, Matthew A., Milinda Abeykoon, AM, Sangoro, Joshua, Baker, Gary A., Nieuwkoop, Andrew J., Margulis, Claudio J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10691361/
https://www.ncbi.nlm.nih.gov/pubmed/37963184
http://dx.doi.org/10.1021/jacs.3c08639
Descripción
Sumario:[Image: see text] High impact recent articles have reported on the existence of a liquid–liquid (L–L) phase transition as a function of both pressure and temperature in ionic liquids (ILs) containing the popular trihexyltetradecylphosphonium cation (P(666,14)(+)), sometimes referred to as the “universal liquifier”. The work presented here reports on the structural-dynamic pathway from liquid to glass of the most well-studied IL comprising the P(666,14)(+) cation. We present experimental and computational evidence that, on cooling, the path from the room-temperature liquid to the glass state is one of separate structural-dynamic changes. The first stage involves the slowdown of the charge network, while the apolar subcomponent is fully mobile. A second, separate stage entails the slowdown of the apolar domain. Whereas it is possible that these processes may be related to the liquid–liquid and glass transitions, more research is needed to establish this conclusively.