Cargando…

Selective C(sp(3))–H arylation/alkylation of alkanes enabled by paired electrocatalysis

We report a combination of electrocatalysis and photoredox catalysis to perform selective C(sp(3))–H arylation/alkylation of alkanes, in which a binary catalytic system based on earth-abundant iron and nickel is applied. Reaction selectivity between two-component C(sp(3))–H arylation and three-compo...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zou, Long, Xiang, Siqi, Sun, Rui, Lu, Qingquan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10693613/ https://www.ncbi.nlm.nih.gov/pubmed/38042911 http://dx.doi.org/10.1038/s41467-023-43791-1

Ejemplares similares

Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes
por: Cao, Hui, et al.
Publicado: (2020)

Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
por: Choi, Isaac, et al.
Publicado: (2021)

Highly selective α-aryloxyalkyl C–H functionalisation of aryl alkyl ethers
por: Bell, Jonathan D., et al.
Publicado: (2022)

Site-Selective C–H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence
por: Lansbergen, Beatrice, et al.
Publicado: (2021)

Late-stage C(sp(2))–H and C(sp(3))–H glycosylation of C-aryl/alkyl glycopeptides: mechanistic insights and fluorescence labeling
por: Wu, Jun, et al.
Publicado: (2020)

Rh(ii)-catalyzed branch-selective C–H alkylation of aryl sulfonamides with vinylsilanes
por: Rej, Supriya, et al.
Publicado: (2019)

Site‐Selective C−H Arylation of Diverse Arenes Ortho to Small Alkyl Groups
por: Dhankhar, Jyoti, et al.
Publicado: (2022)

Chemo‐ and Site‐Selective Electro‐Oxidative Alkane Fluorination by C(sp(3))−H Cleavage
por: Stangier, Maximilian, et al.
Publicado: (2022)

Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
por: Li, Yanjun, et al.
Publicado: (2021)

Temperature-modulated selective C(sp(3))–H or C(sp(2))–H arylation through palladium catalysis
por: Gogula, Thirupathi, et al.
Publicado: (2020)

C(sp(3))–C(sp(2)) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates
por: Vara, Brandon A., et al.
Publicado: (2017)

Paired electrocatalysis in 5-hydroxymethylfurfural valorization
por: Qu, Dalong, et al.
Publicado: (2022)

Correction to “Site-Selective C–H Alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence”
por: Lansbergen, Beatrice, et al.
Publicado: (2021)

Copper-Mediated Dehydrogenative C(sp(3))–H Borylation of Alkanes
por: Sang, Ruocheng, et al.
Publicado: (2023)

Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Cobalt-catalyzed C(sp(3))–H/C(sp(2))–H oxidative coupling between alkanes and benzamides
por: Li, Shuangjie, et al.
Publicado: (2018)

Iron-Catalyzed C(sp(2))–C(sp(3)) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents
por: Bisz, Elwira, et al.
Publicado: (2020)

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds
por: Zhang, Lei, et al.
Publicado: (2020)

Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones
por: Kurosawa, Miki B., et al.
Publicado: (2022)

Ligand-Promoted Alkylation of C(sp(3))–H and C(sp(2))–H Bonds
por: Zhu, Ru-Yi, et al.
Publicado: (2014)

Author Correction: Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Dual Electrocatalysis Enables Enantioselective Hydrocyanation of Conjugated Alkenes
por: Song, Lu, et al.
Publicado: (2020)

Radioiodination of Aryl-Alkyl Cyclic Sulfates
por: Mushti, Chandra, et al.
Publicado: (2012)

Multimetallic catalysed radical oxidative C(sp(3))–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
por: Tang, Shan, et al.
Publicado: (2016)

Regioselective synthesis of C3 alkylated and arylated benzothiophenes
por: Shrives, Harry J., et al.
Publicado: (2017)

Dihydroquinazolinones as adaptative C(sp(3)) handles in arylations and alkylations via dual catalytic C–C bond-functionalization
por: Lv, Xin-Yang, et al.
Publicado: (2022)

Site‐Selective Pd‐Catalyzed C(sp(3))−H Arylation of Heteroaromatic Ketones
por: Kudashev, Anton, et al.
Publicado: (2021)

Unraveling the mechanism for paired electrocatalysis of organics with water as a feedstock
por: Yang, Ganceng, et al.
Publicado: (2022)

α-C(sp(3))-H Arylation of Cyclic Carbonyl Compounds
por: Wang, Mei, et al.
Publicado: (2021)

Palladium‐Catalyzed C(sp(3))−H Arylation of Primary Amines Using a Catalytic Alkyl Acetal to Form a Transient Directing Group
por: St John‐Campbell, Sahra, et al.
Publicado: (2018)

Vinyl Cation Stabilization by Silicon Enables a Formal Metal‐Free α‐Arylation of Alkyl Ketones
por: Pons, Amandine, et al.
Publicado: (2019)

Rapid Photoracemization of Chiral Alkyl Aryl Sulfoxides
por: Makino, Kosho, et al.
Publicado: (2021)

The site-selectivity and mechanism of Pd-catalyzed C(sp(2))–H arylation of simple arenes
por: Kim, Daeun, et al.
Publicado: (2020)

Synthesis of a Bicyclic Azetidine with In Vivo Antimalarial Activity Enabled by Stereospecific, Directed C(sp(3))–H Arylation
por: Maetani, Micah, et al.
Publicado: (2017)

Pd-catalyzed cross-electrophile Coupling/C–H alkylation reaction enabled by a mediator generated via C(sp(3))–H activation
por: Wu, Zhuo, et al.
Publicado: (2021)

Photocatalytic Alkylation of C(sp(3))−H Bonds Using Sulfonylhydrazones
por: Pulcinella, Antonio, et al.
Publicado: (2022)

Plasmonic Silver‐Nanoparticle‐Catalysed Hydrogen Abstraction from the C(sp ( 3 ))−H Bond of the Benzylic C(α) atom for Cleavage of Alkyl Aryl Ether Bonds
por: Han, Pengfei, et al.
Publicado: (2022)

Selective oxidation of alkyl and aryl glyceryl monoethers catalysed by an engineered and immobilised glycerol dehydrogenase
por: Velasco-Lozano, Susana, et al.
Publicado: (2020)

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air
por: Kalvet, Indrek, et al.
Publicado: (2017)

Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates
por: He, Wei-Bao, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_k6c1j9lk8f02a8vq4lqactaad2