Structural characterization of newly-developed Al(79)Ni(5)Fe(5)Y(11) and Al(79)Ni(11)Fe(5)Y(5) alloys with amorphous matrixes

The low glass-forming ability of aluminium-based metallic glasses significantly limits their development and preparation. This paper updates the current state of knowledge by presenting the results of structural studies of two newly-developed Al(79)Ni(5)Fe(5)Y(11) and Al(79)Ni(11)Fe(5)Y(5) alloys with a reduced aluminium content (< 80 at.%). The alloys were produced by conventional casting (ingots) and melt-spinning (ribbons). Structural characterization was carried out for bulk ingots first, and then for the melt-spun ribbons. The ingots possessed a multiphase crystalline structure, as confirmed by X-ray diffraction and scanning electron microscopy observations. The amorphous structure of the melt-spun ribbons was determined by X-ray diffraction and transmission electron microscopy. SEM observations and EDX element maps of the cross-section of melt-spun ribbons indicated a homogeneous elemental composition. Neutron diffraction revealed the presence of nanocrystals in the amorphous matrix of the melt-spun ribbons. DSC data of the melt-spun ribbons showed exothermic events corresponding to the first crystallization at temperatures of 408 °C and 387 °C for Al(79)Ni(5)Fe(5)Y(11) and Al(79)Ni(11)Fe(5)Y(5), respectively.