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Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin

Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 1...

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Autores principales: Hirose, Takuji, Kikuchi, Yuka, Nakano, Tomoaki, Ohno, Tsukasa, Kawamura, Kengo, Nazri, Normazliana Binti, Fujimori, Atsuhiro, Kodama, Koichi, Yasutake, Mikio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10694167/
http://dx.doi.org/10.1016/j.heliyon.2023.e22037
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author Hirose, Takuji
Kikuchi, Yuka
Nakano, Tomoaki
Ohno, Tsukasa
Kawamura, Kengo
Nazri, Normazliana Binti
Fujimori, Atsuhiro
Kodama, Koichi
Yasutake, Mikio
author_facet Hirose, Takuji
Kikuchi, Yuka
Nakano, Tomoaki
Ohno, Tsukasa
Kawamura, Kengo
Nazri, Normazliana Binti
Fujimori, Atsuhiro
Kodama, Koichi
Yasutake, Mikio
author_sort Hirose, Takuji
collection PubMed
description Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 110 °C in the Col(r) temperature range. The apparent photoreaction products were shown to be thermally reversible, i.e. they dissolved in liquid paraffin at high temperatures and reappeared on cooling, indicating that they were aggregates of oligomerized TPC1(p)-n. The reaction mechanism was discussed in terms of the structure of the liquid crystalline phase.
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spelling pubmed-106941672023-12-05 Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin Hirose, Takuji Kikuchi, Yuka Nakano, Tomoaki Ohno, Tsukasa Kawamura, Kengo Nazri, Normazliana Binti Fujimori, Atsuhiro Kodama, Koichi Yasutake, Mikio Heliyon Research Article Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 110 °C in the Col(r) temperature range. The apparent photoreaction products were shown to be thermally reversible, i.e. they dissolved in liquid paraffin at high temperatures and reappeared on cooling, indicating that they were aggregates of oligomerized TPC1(p)-n. The reaction mechanism was discussed in terms of the structure of the liquid crystalline phase. Elsevier 2023-11-10 /pmc/articles/PMC10694167/ http://dx.doi.org/10.1016/j.heliyon.2023.e22037 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Hirose, Takuji
Kikuchi, Yuka
Nakano, Tomoaki
Ohno, Tsukasa
Kawamura, Kengo
Nazri, Normazliana Binti
Fujimori, Atsuhiro
Kodama, Koichi
Yasutake, Mikio
Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title_full Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title_fullStr Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title_full_unstemmed Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title_short Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
title_sort thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10694167/
http://dx.doi.org/10.1016/j.heliyon.2023.e22037
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