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Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin
Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 1...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10694167/ http://dx.doi.org/10.1016/j.heliyon.2023.e22037 |
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author | Hirose, Takuji Kikuchi, Yuka Nakano, Tomoaki Ohno, Tsukasa Kawamura, Kengo Nazri, Normazliana Binti Fujimori, Atsuhiro Kodama, Koichi Yasutake, Mikio |
author_facet | Hirose, Takuji Kikuchi, Yuka Nakano, Tomoaki Ohno, Tsukasa Kawamura, Kengo Nazri, Normazliana Binti Fujimori, Atsuhiro Kodama, Koichi Yasutake, Mikio |
author_sort | Hirose, Takuji |
collection | PubMed |
description | Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 110 °C in the Col(r) temperature range. The apparent photoreaction products were shown to be thermally reversible, i.e. they dissolved in liquid paraffin at high temperatures and reappeared on cooling, indicating that they were aggregates of oligomerized TPC1(p)-n. The reaction mechanism was discussed in terms of the structure of the liquid crystalline phase. |
format | Online Article Text |
id | pubmed-10694167 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-106941672023-12-05 Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin Hirose, Takuji Kikuchi, Yuka Nakano, Tomoaki Ohno, Tsukasa Kawamura, Kengo Nazri, Normazliana Binti Fujimori, Atsuhiro Kodama, Koichi Yasutake, Mikio Heliyon Research Article Liquid crystalline triphenylene derivatives, TPC1(p)-n (n = 6, 12, 14, 16) were prepared using p-alkoxycinnamate as the [2+2] photo-cyclization site. TPC1(p)-n (n = 12, 14, 16) showed Col(r) phase and gave crescent-shaped or helical fibers after UV-irradiated in liquid paraffin solutions at 90 and 110 °C in the Col(r) temperature range. The apparent photoreaction products were shown to be thermally reversible, i.e. they dissolved in liquid paraffin at high temperatures and reappeared on cooling, indicating that they were aggregates of oligomerized TPC1(p)-n. The reaction mechanism was discussed in terms of the structure of the liquid crystalline phase. Elsevier 2023-11-10 /pmc/articles/PMC10694167/ http://dx.doi.org/10.1016/j.heliyon.2023.e22037 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Research Article Hirose, Takuji Kikuchi, Yuka Nakano, Tomoaki Ohno, Tsukasa Kawamura, Kengo Nazri, Normazliana Binti Fujimori, Atsuhiro Kodama, Koichi Yasutake, Mikio Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title | Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title_full | Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title_fullStr | Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title_full_unstemmed | Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title_short | Thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
title_sort | thermoreversible helical fibers from photoreactive triphenylene-derived liquid crystals in liquid paraffin |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10694167/ http://dx.doi.org/10.1016/j.heliyon.2023.e22037 |
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