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Influence of the π–π interaction on the hydrogen bonding capacity of stacked DNA/RNA bases
The interplay between aromatic stacking and hydrogen bonding in nucleobases has been investigated via high-level quantum chemical calculations. The experimentally observed stacking arrangement between consecutive bases in DNA and RNA/DNA double helices is shown to enhance their hydrogen bonding abil...
Autores principales: | Mignon, Pierre, Loverix, Stefan, Steyaert, Jan, Geerlings, Paul |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Oxford University Press
2005
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1069514/ https://www.ncbi.nlm.nih.gov/pubmed/15788750 http://dx.doi.org/10.1093/nar/gki317 |
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