Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids

The macrocyclic amine, 1,5,9,18,22,26-hexaaza [11.11]-p-cyclophane (1) contains two dipropylenetriamine units which make the molecule highly basic. Owing to this basicity, 1 can be highly protonated in acidic media and can form supramolecular assemblies with different anions. Two new supramolecular...

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Autores principales: Borowiak, Teresa, Dutkiewicz, Grzegorz, Kubicki, Maciej, Pietraszkiewicz, Marek, Gil, Agnieszka, Mattes, Rainer
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2005
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1399464/
https://www.ncbi.nlm.nih.gov/pubmed/16551374
http://dx.doi.org/10.1186/1860-5397-1-16
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author Borowiak, Teresa
Dutkiewicz, Grzegorz
Kubicki, Maciej
Pietraszkiewicz, Marek
Gil, Agnieszka
Mattes, Rainer
author_facet Borowiak, Teresa
Dutkiewicz, Grzegorz
Kubicki, Maciej
Pietraszkiewicz, Marek
Gil, Agnieszka
Mattes, Rainer
author_sort Borowiak, Teresa
collection PubMed
description The macrocyclic amine, 1,5,9,18,22,26-hexaaza [11.11]-p-cyclophane (1) contains two dipropylenetriamine units which make the molecule highly basic. Owing to this basicity, 1 can be highly protonated in acidic media and can form supramolecular assemblies with different anions. Two new supramolecular structures arise from self-assembly of the salt of 1 with fumaric acid and of the N-methyl derivative of 1.
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spelling pubmed-13994642006-03-13 Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids Borowiak, Teresa Dutkiewicz, Grzegorz Kubicki, Maciej Pietraszkiewicz, Marek Gil, Agnieszka Mattes, Rainer Beilstein J Org Chem Full Research Paper The macrocyclic amine, 1,5,9,18,22,26-hexaaza [11.11]-p-cyclophane (1) contains two dipropylenetriamine units which make the molecule highly basic. Owing to this basicity, 1 can be highly protonated in acidic media and can form supramolecular assemblies with different anions. Two new supramolecular structures arise from self-assembly of the salt of 1 with fumaric acid and of the N-methyl derivative of 1. Beilstein-Institut 2005-12-09 /pmc/articles/PMC1399464/ /pubmed/16551374 http://dx.doi.org/10.1186/1860-5397-1-16 Text en Copyright © 2005, Borowiak et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Borowiak, Teresa
Dutkiewicz, Grzegorz
Kubicki, Maciej
Pietraszkiewicz, Marek
Gil, Agnieszka
Mattes, Rainer
Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title_full Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title_fullStr Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title_full_unstemmed Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title_short Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
title_sort molecular recognition. 1. crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1399464/
https://www.ncbi.nlm.nih.gov/pubmed/16551374
http://dx.doi.org/10.1186/1860-5397-1-16
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