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Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described.
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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Beilstein-Institut
2006
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1408083/ https://www.ncbi.nlm.nih.gov/pubmed/16542010 http://dx.doi.org/10.1186/1860-5397-2-1 |
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author | Slana, Glaucia Barbosa Candido Alves de Azevedo, Mariângela Soares Lopes, Rosângela Sabattini Capella Lopes, Cláudio Cerqueira Cardoso, Jari Nobrega |
author_facet | Slana, Glaucia Barbosa Candido Alves de Azevedo, Mariângela Soares Lopes, Rosângela Sabattini Capella Lopes, Cláudio Cerqueira Cardoso, Jari Nobrega |
author_sort | Slana, Glaucia Barbosa Candido Alves |
collection | PubMed |
description | Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described. |
format | Text |
id | pubmed-1408083 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2006 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-14080832006-03-23 Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates Slana, Glaucia Barbosa Candido Alves de Azevedo, Mariângela Soares Lopes, Rosângela Sabattini Capella Lopes, Cláudio Cerqueira Cardoso, Jari Nobrega Beilstein J Org Chem Full Research Paper Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described. Beilstein-Institut 2006-02-21 /pmc/articles/PMC1408083/ /pubmed/16542010 http://dx.doi.org/10.1186/1860-5397-2-1 Text en Copyright © 2006, Slana et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Slana, Glaucia Barbosa Candido Alves de Azevedo, Mariângela Soares Lopes, Rosângela Sabattini Capella Lopes, Cláudio Cerqueira Cardoso, Jari Nobrega Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title | Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title_full | Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title_fullStr | Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title_full_unstemmed | Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title_short | Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates |
title_sort | total syntheses of oxygenated brazanquinones via regioselective homologous anionic fries rearrangement of benzylic o-carbamates |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1408083/ https://www.ncbi.nlm.nih.gov/pubmed/16542010 http://dx.doi.org/10.1186/1860-5397-2-1 |
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