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Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates

Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described.

Detalles Bibliográficos
Autores principales: Slana, Glaucia Barbosa Candido Alves, de Azevedo, Mariângela Soares, Lopes, Rosângela Sabattini Capella, Lopes, Cláudio Cerqueira, Cardoso, Jari Nobrega
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2006
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1408083/
https://www.ncbi.nlm.nih.gov/pubmed/16542010
http://dx.doi.org/10.1186/1860-5397-2-1
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author Slana, Glaucia Barbosa Candido Alves
de Azevedo, Mariângela Soares
Lopes, Rosângela Sabattini Capella
Lopes, Cláudio Cerqueira
Cardoso, Jari Nobrega
author_facet Slana, Glaucia Barbosa Candido Alves
de Azevedo, Mariângela Soares
Lopes, Rosângela Sabattini Capella
Lopes, Cláudio Cerqueira
Cardoso, Jari Nobrega
author_sort Slana, Glaucia Barbosa Candido Alves
collection PubMed
description Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described.
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spelling pubmed-14080832006-03-23 Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates Slana, Glaucia Barbosa Candido Alves de Azevedo, Mariângela Soares Lopes, Rosângela Sabattini Capella Lopes, Cláudio Cerqueira Cardoso, Jari Nobrega Beilstein J Org Chem Full Research Paper Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from β-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described. Beilstein-Institut 2006-02-21 /pmc/articles/PMC1408083/ /pubmed/16542010 http://dx.doi.org/10.1186/1860-5397-2-1 Text en Copyright © 2006, Slana et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Slana, Glaucia Barbosa Candido Alves
de Azevedo, Mariângela Soares
Lopes, Rosângela Sabattini Capella
Lopes, Cláudio Cerqueira
Cardoso, Jari Nobrega
Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title_full Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title_fullStr Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title_full_unstemmed Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title_short Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates
title_sort total syntheses of oxygenated brazanquinones via regioselective homologous anionic fries rearrangement of benzylic o-carbamates
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1408083/
https://www.ncbi.nlm.nih.gov/pubmed/16542010
http://dx.doi.org/10.1186/1860-5397-2-1
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