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Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR

The use of organophosphorus derivatising agents, prepared from C(2) symmetric trimethylsilylated diamines, for the (1)H NMR and (31)P NMR determination of the enantiomeric composition of chiral alcohols is described.

Detalles Bibliográficos
Autores principales: Chauvin, Anne-Sophie, Alexakis, Alexandre
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2006
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1483824/
https://www.ncbi.nlm.nih.gov/pubmed/16566844
http://dx.doi.org/10.1186/1860-5397-2-6
Descripción
Sumario:The use of organophosphorus derivatising agents, prepared from C(2) symmetric trimethylsilylated diamines, for the (1)H NMR and (31)P NMR determination of the enantiomeric composition of chiral alcohols is described.