Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR

The use of organophosphorus derivatising agents, prepared from C(2) symmetric trimethylsilylated diamines, for the (1)H NMR and (31)P NMR determination of the enantiomeric composition of chiral alcohols is described.

Detalles Bibliográficos
Autores principales: Chauvin, Anne-Sophie, Alexakis, Alexandre
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2006
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1483824/
https://www.ncbi.nlm.nih.gov/pubmed/16566844
http://dx.doi.org/10.1186/1860-5397-2-6
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author Chauvin, Anne-Sophie
Alexakis, Alexandre
author_facet Chauvin, Anne-Sophie
Alexakis, Alexandre
author_sort Chauvin, Anne-Sophie
collection PubMed
description The use of organophosphorus derivatising agents, prepared from C(2) symmetric trimethylsilylated diamines, for the (1)H NMR and (31)P NMR determination of the enantiomeric composition of chiral alcohols is described.
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spelling pubmed-14838242006-06-29 Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR Chauvin, Anne-Sophie Alexakis, Alexandre Beilstein J Org Chem Full Research Paper The use of organophosphorus derivatising agents, prepared from C(2) symmetric trimethylsilylated diamines, for the (1)H NMR and (31)P NMR determination of the enantiomeric composition of chiral alcohols is described. Beilstein-Institut 2006-03-28 /pmc/articles/PMC1483824/ /pubmed/16566844 http://dx.doi.org/10.1186/1860-5397-2-6 Text en Copyright © 2006, Chauvin and Alexakis https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Chauvin, Anne-Sophie
Alexakis, Alexandre
Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title_full Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title_fullStr Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title_full_unstemmed Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title_short Chiral trimethylsilylated C(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)H NMR
title_sort chiral trimethylsilylated c(2)-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by (1)h nmr
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1483824/
https://www.ncbi.nlm.nih.gov/pubmed/16566844
http://dx.doi.org/10.1186/1860-5397-2-6
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AT alexakisalexandre chiraltrimethylsilylatedc2symmetricaldiaminesasphosphorousderivatizingagentsforthedeterminationoftheenantiomericexcessofchiralalcoholsby1hnmr

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