Reductive dehalogenation of bromoform in aqueous solution.

The hybrid semiconducter-macrocycle catalyst TiO2-cobalt phthalocyanine promotes the solar photolysis of aqueous bromoform under anaerobic conditions. The major decomposition products are dibromoethane and HBr. Bromomethane and methane were produced only after prolonged photolysis (30 hr). Acetone,...

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Detalles Bibliográficos
Autores principales: Betterton, E A, Arnold, R G, Kuhler, R J, Santo, G A
Formato: Texto
Lenguaje:English
Publicado: 1995
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1519304/
https://www.ncbi.nlm.nih.gov/pubmed/8565919
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author Betterton, E A
Arnold, R G
Kuhler, R J
Santo, G A
author_facet Betterton, E A
Arnold, R G
Kuhler, R J
Santo, G A
author_sort Betterton, E A
collection PubMed
description The hybrid semiconducter-macrocycle catalyst TiO2-cobalt phthalocyanine promotes the solar photolysis of aqueous bromoform under anaerobic conditions. The major decomposition products are dibromoethane and HBr. Bromomethane and methane were produced only after prolonged photolysis (30 hr). Acetone, derived from added 2-propanol, was the only observed oxidation product. Preliminary experiments showed that electrolytic reduction of aqueous carbon tetrachloride at a vitamin B12-modified silver electrode produced the expected lower homologues but with surprisingly high yields of methane.
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spelling pubmed-15193042006-07-28 Reductive dehalogenation of bromoform in aqueous solution. Betterton, E A Arnold, R G Kuhler, R J Santo, G A Environ Health Perspect Research Article The hybrid semiconducter-macrocycle catalyst TiO2-cobalt phthalocyanine promotes the solar photolysis of aqueous bromoform under anaerobic conditions. The major decomposition products are dibromoethane and HBr. Bromomethane and methane were produced only after prolonged photolysis (30 hr). Acetone, derived from added 2-propanol, was the only observed oxidation product. Preliminary experiments showed that electrolytic reduction of aqueous carbon tetrachloride at a vitamin B12-modified silver electrode produced the expected lower homologues but with surprisingly high yields of methane. 1995-06 /pmc/articles/PMC1519304/ /pubmed/8565919 Text en
spellingShingle Research Article
Betterton, E A
Arnold, R G
Kuhler, R J
Santo, G A
Reductive dehalogenation of bromoform in aqueous solution.
title Reductive dehalogenation of bromoform in aqueous solution.
title_full Reductive dehalogenation of bromoform in aqueous solution.
title_fullStr Reductive dehalogenation of bromoform in aqueous solution.
title_full_unstemmed Reductive dehalogenation of bromoform in aqueous solution.
title_short Reductive dehalogenation of bromoform in aqueous solution.
title_sort reductive dehalogenation of bromoform in aqueous solution.
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1519304/
https://www.ncbi.nlm.nih.gov/pubmed/8565919
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AT kuhlerrj reductivedehalogenationofbromoforminaqueoussolution
AT santoga reductivedehalogenationofbromoforminaqueoussolution

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