Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium

The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid c...

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Detalles Bibliográficos
Autores principales: Pégot, Bruce, Van Buu, Olivier Nguyen, Gori, Didier, Vo-Thanh, Giang
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2006
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1592496/
https://www.ncbi.nlm.nih.gov/pubmed/16982000
http://dx.doi.org/10.1186/1860-5397-2-18
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author Pégot, Bruce
Van Buu, Olivier Nguyen
Gori, Didier
Vo-Thanh, Giang
author_facet Pégot, Bruce
Van Buu, Olivier Nguyen
Gori, Didier
Vo-Thanh, Giang
author_sort Pégot, Bruce
collection PubMed
description The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid catalyst or organic solvent. Chiral ionic liquids are recycled while their efficiency is preserved.
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spelling pubmed-15924962006-10-07 Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium Pégot, Bruce Van Buu, Olivier Nguyen Gori, Didier Vo-Thanh, Giang Beilstein J Org Chem Preliminary Communication The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid catalyst or organic solvent. Chiral ionic liquids are recycled while their efficiency is preserved. Beilstein-Institut 2006-09-18 /pmc/articles/PMC1592496/ /pubmed/16982000 http://dx.doi.org/10.1186/1860-5397-2-18 Text en Copyright © 2006, Pégot et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Preliminary Communication
Pégot, Bruce
Van Buu, Olivier Nguyen
Gori, Didier
Vo-Thanh, Giang
Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title_full Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title_fullStr Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title_full_unstemmed Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title_short Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
title_sort asymmetric aza-diels-alder reaction of danishefsky's diene with imines in a chiral reaction medium
topic Preliminary Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1592496/
https://www.ncbi.nlm.nih.gov/pubmed/16982000
http://dx.doi.org/10.1186/1860-5397-2-18
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