Reactions of carbanions with triplet and singlet molecular oxygen.

The gas phase reactions of carbanions with molecular oxygen in both its ground state (X3 sigma g-) and first electronically excited state (a1 delta g) have been studied by the flowing afterglow technique. Reactions include cleavage processes, charge transfer, hydride transfer, formation of hydroxide...

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Detalles Bibliográficos
Autores principales: Bierbaum, V M, Schmitt, R J, DePuy, C H
Formato: Texto
Lenguaje:English
Publicado: 1980
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1637747/
https://www.ncbi.nlm.nih.gov/pubmed/7428740
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author Bierbaum, V M
Schmitt, R J
DePuy, C H
author_facet Bierbaum, V M
Schmitt, R J
DePuy, C H
author_sort Bierbaum, V M
collection PubMed
description The gas phase reactions of carbanions with molecular oxygen in both its ground state (X3 sigma g-) and first electronically excited state (a1 delta g) have been studied by the flowing afterglow technique. Reactions include cleavage processes, charge transfer, hydride transfer, formation of hydroxide ion and processes which involve secondary reactions within a long-lived complex. The mechanisms of the reactions are discussed. The usefulness of molecular oxygen as a reagent for the structural degradation and analysis of gas phase organic anions, including isomeric species, is described.
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spelling pubmed-16377472006-11-17 Reactions of carbanions with triplet and singlet molecular oxygen. Bierbaum, V M Schmitt, R J DePuy, C H Environ Health Perspect Research Article The gas phase reactions of carbanions with molecular oxygen in both its ground state (X3 sigma g-) and first electronically excited state (a1 delta g) have been studied by the flowing afterglow technique. Reactions include cleavage processes, charge transfer, hydride transfer, formation of hydroxide ion and processes which involve secondary reactions within a long-lived complex. The mechanisms of the reactions are discussed. The usefulness of molecular oxygen as a reagent for the structural degradation and analysis of gas phase organic anions, including isomeric species, is described. 1980-06 /pmc/articles/PMC1637747/ /pubmed/7428740 Text en
spellingShingle Research Article
Bierbaum, V M
Schmitt, R J
DePuy, C H
Reactions of carbanions with triplet and singlet molecular oxygen.
title Reactions of carbanions with triplet and singlet molecular oxygen.
title_full Reactions of carbanions with triplet and singlet molecular oxygen.
title_fullStr Reactions of carbanions with triplet and singlet molecular oxygen.
title_full_unstemmed Reactions of carbanions with triplet and singlet molecular oxygen.
title_short Reactions of carbanions with triplet and singlet molecular oxygen.
title_sort reactions of carbanions with triplet and singlet molecular oxygen.
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1637747/
https://www.ncbi.nlm.nih.gov/pubmed/7428740
work_keys_str_mv AT bierbaumvm reactionsofcarbanionswithtripletandsingletmolecularoxygen
AT schmittrj reactionsofcarbanionswithtripletandsingletmolecularoxygen
AT depuych reactionsofcarbanionswithtripletandsingletmolecularoxygen

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