Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans

Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoi...

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Autores principales: Álvarez-Corral, Míriam, López-Sánchez, Cristóbal, Jiménez-González, Leticia, Rosales, Antonio, Muñoz-Dorado, Manuel, Rodríguez-García, Ignacio
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810298/
https://www.ncbi.nlm.nih.gov/pubmed/17288601
http://dx.doi.org/10.1186/1860-5397-3-5
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author Álvarez-Corral, Míriam
López-Sánchez, Cristóbal
Jiménez-González, Leticia
Rosales, Antonio
Muñoz-Dorado, Manuel
Rodríguez-García, Ignacio
author_facet Álvarez-Corral, Míriam
López-Sánchez, Cristóbal
Jiménez-González, Leticia
Rosales, Antonio
Muñoz-Dorado, Manuel
Rodríguez-García, Ignacio
author_sort Álvarez-Corral, Míriam
collection PubMed
description Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoid pterocarpans.
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spelling pubmed-18102982007-03-06 Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans Álvarez-Corral, Míriam López-Sánchez, Cristóbal Jiménez-González, Leticia Rosales, Antonio Muñoz-Dorado, Manuel Rodríguez-García, Ignacio Beilstein J Org Chem Full Research Paper Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoid pterocarpans. Beilstein-Institut 2007-02-08 /pmc/articles/PMC1810298/ /pubmed/17288601 http://dx.doi.org/10.1186/1860-5397-3-5 Text en Copyright © 2007, Álvarez-Corral et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Álvarez-Corral, Míriam
López-Sánchez, Cristóbal
Jiménez-González, Leticia
Rosales, Antonio
Muñoz-Dorado, Manuel
Rodríguez-García, Ignacio
Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title_full Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title_fullStr Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title_full_unstemmed Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title_short Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
title_sort reaction of benzoxasilocines with aromatic aldehydes: synthesis of homopterocarpans
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810298/
https://www.ncbi.nlm.nih.gov/pubmed/17288601
http://dx.doi.org/10.1186/1860-5397-3-5
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