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Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans
Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoi...
Autores principales: | Álvarez-Corral, Míriam, López-Sánchez, Cristóbal, Jiménez-González, Leticia, Rosales, Antonio, Muñoz-Dorado, Manuel, Rodríguez-García, Ignacio |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810298/ https://www.ncbi.nlm.nih.gov/pubmed/17288601 http://dx.doi.org/10.1186/1860-5397-3-5 |
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