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Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
In recent years, cyclic silicon-stereogenic silanes were successfully employed as stereoinducers in transition metal-catalyzed asymmetric transformations as exemplified by (1) the hydrosilylation of alkenes constituting a chirality transfer from silicon to carbon and (2) the kinetic resolution of ra...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810299/ https://www.ncbi.nlm.nih.gov/pubmed/17288605 http://dx.doi.org/10.1186/1860-5397-3-9 |